化工技术与开发
化工技術與開髮
화공기술여개발
TECHNOLOGY & DVELOPMENT OF CHEMICAL INDUSTRY
2014年
10期
4-7
,共4页
庞锦英%莫羡忠%刘钰馨%杨芳
龐錦英%莫羨忠%劉鈺馨%楊芳
방금영%막이충%류옥형%양방
香蕉纤维%环氧树脂%阻燃剂%燃烧性能%力学性能
香蕉纖維%環氧樹脂%阻燃劑%燃燒性能%力學性能
향초섬유%배양수지%조연제%연소성능%역학성능
banana fiber%epoxy resin%fire retardant%combustibility%mechanical property
采用正交试验方法分别探讨了阻燃纤维含量、阻燃剂含量、阻燃剂配比、纤维长度对复合材料燃烧性能及力学性能的影响,采用极差分析方法对试验结果进行了分析,找出最佳的配方,然后与其它添加不同种类的阻燃剂的复合材料进行性能比较。结果表明,当纤维长度5mm、阻燃纤维质量为总质量的10%、阻燃剂质量为环氧树脂质量的40%、三聚氰胺焦磷酸盐(MPP)和季戊四醇(PER)配比为3∶1时,复合材料的拉伸强度为20.45MPa,氧指数为33.7,垂直燃烧达到UL94V-O级。燃烧性能和力学性能与环氧树脂相比较,有较为显著的提高,综合性能最好。在纤维长度、阻燃纤维含量、阻燃剂含量都相同的情况下,添加不同种类的阻燃剂,其中添加MPP和季戊四醇的复合材料性能最好。
採用正交試驗方法分彆探討瞭阻燃纖維含量、阻燃劑含量、阻燃劑配比、纖維長度對複閤材料燃燒性能及力學性能的影響,採用極差分析方法對試驗結果進行瞭分析,找齣最佳的配方,然後與其它添加不同種類的阻燃劑的複閤材料進行性能比較。結果錶明,噹纖維長度5mm、阻燃纖維質量為總質量的10%、阻燃劑質量為環氧樹脂質量的40%、三聚氰胺焦燐痠鹽(MPP)和季戊四醇(PER)配比為3∶1時,複閤材料的拉伸彊度為20.45MPa,氧指數為33.7,垂直燃燒達到UL94V-O級。燃燒性能和力學性能與環氧樹脂相比較,有較為顯著的提高,綜閤性能最好。在纖維長度、阻燃纖維含量、阻燃劑含量都相同的情況下,添加不同種類的阻燃劑,其中添加MPP和季戊四醇的複閤材料性能最好。
채용정교시험방법분별탐토료조연섬유함량、조연제함량、조연제배비、섬유장도대복합재료연소성능급역학성능적영향,채용겁차분석방법대시험결과진행료분석,조출최가적배방,연후여기타첨가불동충류적조연제적복합재료진행성능비교。결과표명,당섬유장도5mm、조연섬유질량위총질량적10%、조연제질량위배양수지질량적40%、삼취청알초린산염(MPP)화계무사순(PER)배비위3∶1시,복합재료적랍신강도위20.45MPa,양지수위33.7,수직연소체도UL94V-O급。연소성능화역학성능여배양수지상비교,유교위현저적제고,종합성능최호。재섬유장도、조연섬유함량、조연제함량도상동적정황하,첨가불동충류적조연제,기중첨가MPP화계무사순적복합재료성능최호。
The orthogonal test was used to study the influence of the content of flame-retarded fiber and fire retardant, the mixture ratio of fire retardant, the length of fiber on flammability and mechanical property of composites. The range analysis was used to analysis the result, the best formula was found. The property of composites was compared with the other composites which were added to the different fire retardant. The result indicated when the length of fiber was 5mm, the quality of flame-retarded fiber was 10% of the total quality, the quality of fire retardant was the quality of epoxy resin 40%, the mixture ratio of melamine pyrophosphate (MPP) and pentaerythritol (PER) was 3∶1, the composites tensile strength was 20.45MPa, the limiting oxygen index (LOI) was 33.7, UL94 rating was reached. Compared to the pure epoxy, combustibility and mechanical property was obviously improved. The total properties were the best as the content of flame-retarded fiber and fire retardant, the length of fiber were the same. Added to the composites with the different fire retardant, the composite properties which added the MPP and PER, were the best.