功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2014年
21期
21098-21102
,共5页
方瑞萍%唐辉%苏秋宁%陈瑞瑞%李斌
方瑞萍%唐輝%囌鞦寧%陳瑞瑞%李斌
방서평%당휘%소추저%진서서%리빈
聚丙烯%改性%偶联%明胶%吸附%单宁
聚丙烯%改性%偶聯%明膠%吸附%單寧
취병희%개성%우련%명효%흡부%단저
polypropylene%modification%coupling%gelatin%adsorption%tannic
以聚丙烯无纺布为基材,表面紫外光诱导接枝丙烯酸,又依次通过酰胺化、酰肼化、叠氮化,以及紫外光辐照偶联明胶,得到吸附单宁性能较好的改性材料.通过质量法、傅里叶变换红外光谱、热重/差热及扫描电镜等对基材、中间产物及最终产物进行了官能团测定、结构表征和吸水性能测定,结果表明各步反应均按预期引入了目标官能团,所制备的改性材料对单宁的最大吸附量为84.30 mg/g.
以聚丙烯無紡佈為基材,錶麵紫外光誘導接枝丙烯痠,又依次通過酰胺化、酰肼化、疊氮化,以及紫外光輻照偶聯明膠,得到吸附單寧性能較好的改性材料.通過質量法、傅裏葉變換紅外光譜、熱重/差熱及掃描電鏡等對基材、中間產物及最終產物進行瞭官能糰測定、結構錶徵和吸水性能測定,結果錶明各步反應均按預期引入瞭目標官能糰,所製備的改性材料對單寧的最大吸附量為84.30 mg/g.
이취병희무방포위기재,표면자외광유도접지병희산,우의차통과선알화、선정화、첩담화,이급자외광복조우련명효,득도흡부단저성능교호적개성재료.통과질량법、부리협변환홍외광보、열중/차열급소묘전경등대기재、중간산물급최종산물진행료관능단측정、결구표정화흡수성능측정,결과표명각보반응균안예기인입료목표관능단,소제비적개성재료대단저적최대흡부량위84.30 mg/g.
Polypropylene non-woven fabric was used as substrate,acrylic acid was grafted onto the PP films via UV irradiation,followed by amidate,hydrazide,azidation and coupling gelatin molecules via UV irradiation. The material with good adsorption performance for tannin acid was obtained.Weighing method,Fourier trans-form infrared spectroscopy,thermogravimentry-differential thermogravimetry and scanning electron microscopy were used to measure functional groups,characterize structures and hygroscopic property of the substrate,in-termediate and final products.The results show that all the reactions introduced target groups according to the prospection,the maximum adsroption of modified material for tannin acid was 84.30 mg/g.