粉末冶金材料科学与工程
粉末冶金材料科學與工程
분말야금재료과학여공정
POWDER METALLURGY MATERIALS SCIENCE AND ENGINEERING
2014年
5期
681-686
,共6页
禹辉锆%曹顺华%金莹%朱杰
禹輝鋯%曹順華%金瑩%硃傑
우휘고%조순화%금형%주걸
梯度钨基重合金%液相迁移%晶粒尺寸梯度%界面张力梯度
梯度鎢基重閤金%液相遷移%晶粒呎吋梯度%界麵張力梯度
제도오기중합금%액상천이%정립척촌제도%계면장력제도
graded tungsten heavy alloy%liquid phase migration%grain size gradient%interface tension gradient
在液相烧结制备的含Mo梯度W-Ni-Fe合金中,对液相迁移或液相再分布的控制极为关键。液相迁移的驱动力为液相迁移压(Pm),而液相迁移压主要由界面张力和晶粒尺寸的变化所引起。本研究从实验角度探究W(Mo)-Ni-Fe体系中界面张力和晶粒尺寸对液相迁移的影响,并通过动力学模型来描述Mo的扩散和液相迁移。结果表明界面张力梯度与晶粒尺寸梯度均有助于液相的迁移,并且算得由晶粒尺寸和Mo分布梯度诱导的液相迁移速率分别为4.807×10-4 kg/m2s和8.117×10-4 kg/m2s。
在液相燒結製備的含Mo梯度W-Ni-Fe閤金中,對液相遷移或液相再分佈的控製極為關鍵。液相遷移的驅動力為液相遷移壓(Pm),而液相遷移壓主要由界麵張力和晶粒呎吋的變化所引起。本研究從實驗角度探究W(Mo)-Ni-Fe體繫中界麵張力和晶粒呎吋對液相遷移的影響,併通過動力學模型來描述Mo的擴散和液相遷移。結果錶明界麵張力梯度與晶粒呎吋梯度均有助于液相的遷移,併且算得由晶粒呎吋和Mo分佈梯度誘導的液相遷移速率分彆為4.807×10-4 kg/m2s和8.117×10-4 kg/m2s。
재액상소결제비적함Mo제도W-Ni-Fe합금중,대액상천이혹액상재분포적공제겁위관건。액상천이적구동력위액상천이압(Pm),이액상천이압주요유계면장력화정립척촌적변화소인기。본연구종실험각도탐구W(Mo)-Ni-Fe체계중계면장력화정립척촌대액상천이적영향,병통과동역학모형래묘술Mo적확산화액상천이。결과표명계면장력제도여정립척촌제도균유조우액상적천이,병차산득유정립척촌화Mo분포제도유도적액상천이속솔분별위4.807×10-4 kg/m2s화8.117×10-4 kg/m2s。
The control of liquid phase migration or liquid redistribution is crucial for the fabrication of graded W-Ni-Fe alloys with Mo addition by liquid phase sintering. The driving force of liquid phase migration is liquid migration pressure Pm which depends on the variation of interfacial tension and grain size. In the present paper, the effects of interfacial tension and grain size on liquid phase migration have been studied experimentally for W (Mo)-Ni-Fe system. A kinetic model was used to describe the diffusion of Mo and the migration of liquid phase. The results show that both the gradient of interfacial tension and grain size are contributed to the migration of liquid phase. The migration velocities of liquid phase induced by gradient of grain size and Mo distribution were calculated respectively.