环境工程技术学报
環境工程技術學報
배경공정기술학보
JOURNAL OF ENVIR0NMENTAL ENGINEERING TECHNOLOGY
2014年
6期
462-466
,共5页
邓文叶%谢永新%李守柱%赵海燕%吕任生%蔺尾燕
鄧文葉%謝永新%李守柱%趙海燕%呂任生%藺尾燕
산문협%사영신%리수주%조해연%려임생%린미연
流化床粉煤灰(CFBFA)%化学组成%形貌%油水分离废水%去油率
流化床粉煤灰(CFBFA)%化學組成%形貌%油水分離廢水%去油率
류화상분매회(CFBFA)%화학조성%형모%유수분리폐수%거유솔
circulating fluidized bed fly ashes(CFBFA)%composition%morphology%oil-water separation wastewater%oil removal rate
选取2种新疆循环流化床粉煤灰(CFBFA),采用化学分析、X 射线衍射分析和扫描电镜对其组成和形貌进行表征。采用氯化铁和氯化铝水溶液对 CFBFA 进行改性,考察改性 CFBFA 的粒径及投加量对新疆克拉玛依油田三采聚驱油水分离废水处理效率的影响。结果表明,CFBFA 中 SiO2、A12 O3、Fe2 O3、CaO 和 MgO 占总质量的90%左右,其玻璃相含量较低,颗粒形状多数不规则,表面粗糙;粒径≤0.074 mm 的改性 CFBFA 对油水分离废水中油的去除效果最好;随着粉煤灰投加量的增加去油率上升,投加量达0.1 g/mL 时去油率达90%以上。
選取2種新疆循環流化床粉煤灰(CFBFA),採用化學分析、X 射線衍射分析和掃描電鏡對其組成和形貌進行錶徵。採用氯化鐵和氯化鋁水溶液對 CFBFA 進行改性,攷察改性 CFBFA 的粒徑及投加量對新疆剋拉瑪依油田三採聚驅油水分離廢水處理效率的影響。結果錶明,CFBFA 中 SiO2、A12 O3、Fe2 O3、CaO 和 MgO 佔總質量的90%左右,其玻璃相含量較低,顆粒形狀多數不規則,錶麵粗糙;粒徑≤0.074 mm 的改性 CFBFA 對油水分離廢水中油的去除效果最好;隨著粉煤灰投加量的增加去油率上升,投加量達0.1 g/mL 時去油率達90%以上。
선취2충신강순배류화상분매회(CFBFA),채용화학분석、X 사선연사분석화소묘전경대기조성화형모진행표정。채용록화철화록화려수용액대 CFBFA 진행개성,고찰개성 CFBFA 적립경급투가량대신강극랍마의유전삼채취구유수분리폐수처리효솔적영향。결과표명,CFBFA 중 SiO2、A12 O3、Fe2 O3、CaO 화 MgO 점총질량적90%좌우,기파리상함량교저,과립형상다수불규칙,표면조조;립경≤0.074 mm 적개성 CFBFA 대유수분리폐수중유적거제효과최호;수착분매회투가량적증가거유솔상승,투가량체0.1 g/mL 시거유솔체90%이상。
The composition and morphology of two kinds of circulating fluidized bed fly ash (CFBFA) in Xinjiang were investigated by X-ray diffraction, scanning electron microscope and chemical analysis methods.The CFBFA were modified by adding FeCl3 and AlCl3 water solution, the particle size and dosages of these modified CFBFA on the treatment efficiency of oil-water separation wastewater from Xinjiang Karamay polymer flooding oilfield were also investigated.The experiment results showed that these CFBFA has the contents of SiO2 , Al2 O3 , Fe2 O3 , CaO and MgO accounting for more than 90% of the total weight, lower content of glass phase, irregular particle shape and rough surface; the particle size of the modified CFBFA below 0.074 mm with good removal effect, the removal rate increased with the increasing of the dosage; when the dosage was 0.1 g/mL in the wastewater, the removal rate reached more than 90%.