CAJ | 학술논문

采用SnCl4·5H2 O、CaCl2·2H2 O、NaOH为原料，表面活性剂PVP作为软模板，通过一个简单的水热过程合成出具有凹心立方形貌的Ca[ Sn( OH)6]微晶。样品的XRD和TEM 表征结果表明水热温度、水热时间、不同的碱源和表面活性剂对产物的形貌和尺度有一定的影响。初步讨论了凹心立方形貌的Ca[ Sn( OH)6]微晶可能的形成机理。
채용SnCl4·5H2 O、CaCl2·2H2 O、NaOH위원료，표면활성제PVP작위연모판，통과일개간단적수열과정합성출구유요심립방형모적Ca[ Sn( OH)6]미정。양품적XRD화TEM 표정결과표명수열온도、수열시간、불동적감원화표면활성제대산물적형모화척도유일정적영향。초보토론료요심립방형모적Ca[ Sn( OH)6]미정가능적형성궤리。
Sunken heart cube-like Ca[Sn(OH)6]microcrystals were prepared via a simple hydrothermal process,with SnCl4· 5H2 O、CaCl2·2H2 O、NaOH as raw materials and assisted with PVP. The influences of the hydrothermal temperature and time,the types of alkali and surfactant were studied according to results of XRD,TEM and SEM. The possible growth mechanisms of sunken heart cube-like microcrystals were discussed preliminarily.