科技创新导报
科技創新導報
과기창신도보
SCIENCE AND TECHNOLOGY CONSULTING HERALD
2014年
26期
24-28,30
,共6页
吴仲斯%靳小虎%周勤%蔡展航
吳仲斯%靳小虎%週勤%蔡展航
오중사%근소호%주근%채전항
突发性污染%铜%镉%铊%强化混凝%高铁酸钾
突髮性汙染%銅%鎘%鉈%彊化混凝%高鐵痠鉀
돌발성오염%동%력%사%강화혼응%고철산갑
sudden polution%copper%cadmium%thalium%enhanced coagulation%potassium ferrate
为应对可能出现的突发性铜+镉+铊复合型污染事件,模拟自来水厂常规工艺以及强化工艺对含有铜(Cu)、镉(Cd)和铊(Tl)的原水进行处理。结果表明,常规工艺对含Cu、Cd和Tl复合污染的原水去除效果有限;Cu的去除较Cd和Tl容易;投加高铁酸钾预处理对Cd和Tl有明显去除效果;Cu、Cd和Tl的去除率随pH的升高而提高。单因素实验和正交试验确定最佳去除方案为高铁酸钾投加1.25mg/L,pH为9.50,PAFC投加2.0mg/L,粉末活性炭投加20mg/L,在此条件下处理含铜4.84mg/L、镉14.10ug/L、铊0.325ug/L的原水,出水剩余铜、镉、铊的浓度分别低于1mg/L、0.005mg/L、0.1ug/L,都达到国家饮用水标准。
為應對可能齣現的突髮性銅+鎘+鉈複閤型汙染事件,模擬自來水廠常規工藝以及彊化工藝對含有銅(Cu)、鎘(Cd)和鉈(Tl)的原水進行處理。結果錶明,常規工藝對含Cu、Cd和Tl複閤汙染的原水去除效果有限;Cu的去除較Cd和Tl容易;投加高鐵痠鉀預處理對Cd和Tl有明顯去除效果;Cu、Cd和Tl的去除率隨pH的升高而提高。單因素實驗和正交試驗確定最佳去除方案為高鐵痠鉀投加1.25mg/L,pH為9.50,PAFC投加2.0mg/L,粉末活性炭投加20mg/L,在此條件下處理含銅4.84mg/L、鎘14.10ug/L、鉈0.325ug/L的原水,齣水剩餘銅、鎘、鉈的濃度分彆低于1mg/L、0.005mg/L、0.1ug/L,都達到國傢飲用水標準。
위응대가능출현적돌발성동+력+사복합형오염사건,모의자래수엄상규공예이급강화공예대함유동(Cu)、력(Cd)화사(Tl)적원수진행처리。결과표명,상규공예대함Cu、Cd화Tl복합오염적원수거제효과유한;Cu적거제교Cd화Tl용역;투가고철산갑예처리대Cd화Tl유명현거제효과;Cu、Cd화Tl적거제솔수pH적승고이제고。단인소실험화정교시험학정최가거제방안위고철산갑투가1.25mg/L,pH위9.50,PAFC투가2.0mg/L,분말활성탄투가20mg/L,재차조건하처리함동4.84mg/L、력14.10ug/L、사0.325ug/L적원수,출수잉여동、력、사적농도분별저우1mg/L、0.005mg/L、0.1ug/L,도체도국가음용수표준。
To respond to accidental copper+cadmium+thallium compound pollution incidents,Simulated conventional water treatment processes and enhanced coagulation process were used to study the removal effect of copper+cadmium+thalium compound polution raw water.The results showed that the removal efficiency of copper/cadmium and thalium by conventional coagulation-sedimentation was poor;copper is easier to be removed than cadmium and thalium;The removal rates of copper/cadmium and thalium increase with pH value rising.Single factor analysis and orthogonal test determine the optimal dosage of K2FeO4,power activated carbon and poly aluminum ferric chloride(PAFC)were 1.25 mg/L,20.0mg/L and 1.50mg/L,the optimal pH was adjusted to 9.50.Under these conditions,the raw water with4.84 mg/L Cu,14.10ug/L Cd and 0.325μg/L Tl could be treated up to the national drinking water standards, with the residual concentration of Cu,Cd and Tl were lower than 1 mg/L,0.005 mg/L and 0.1ug/L.