江苏科技大学学报(自然科学版)
江囌科技大學學報(自然科學版)
강소과기대학학보(자연과학판)
JOURNAL OF JIANGSU UNIVERSITY OF SCIENCE AND TECHNOLOGY(NATURAL SCIENCE EDITION)
2014年
4期
337-341
,共5页
闫博%张龙梅%张俊豪
閆博%張龍梅%張俊豪
염박%장룡매%장준호
催化分解%纳米片%拉曼谱%透射电镜%N2 吸附脱附等温线
催化分解%納米片%拉曼譜%透射電鏡%N2 吸附脫附等溫線
최화분해%납미편%랍만보%투사전경%N2 흡부탈부등온선
catalytic pyrolysis%carbon nanosheets%Raman spectroscopy%transmission electron microscope%N2 adsorption-desorption isotherm
以二茂铁为催化剂和碳源,硫粉为辅助剂,采用催化分解技术,在500°C时制备碳纳米片,成炭率高达95%左右.结构测试结果表明:酸处理后的主要产物为非晶碳纳米片,其厚度约为40 nm.氮气吸附脱附结果表明:合成的碳纳米片为介孔材料的特征吸附脱附等温线,比表面积为41.1 m2/g,孔径主要集中在3.5~5 nm.
以二茂鐵為催化劑和碳源,硫粉為輔助劑,採用催化分解技術,在500°C時製備碳納米片,成炭率高達95%左右.結構測試結果錶明:痠處理後的主要產物為非晶碳納米片,其厚度約為40 nm.氮氣吸附脫附結果錶明:閤成的碳納米片為介孔材料的特徵吸附脫附等溫線,比錶麵積為41.1 m2/g,孔徑主要集中在3.5~5 nm.
이이무철위최화제화탄원,류분위보조제,채용최화분해기술,재500°C시제비탄납미편,성탄솔고체95%좌우.결구측시결과표명:산처리후적주요산물위비정탄납미편,기후도약위40 nm.담기흡부탈부결과표명:합성적탄납미편위개공재료적특정흡부탈부등온선,비표면적위41.1 m2/g,공경주요집중재3.5~5 nm.
A catalytic pyrolysis approach was developed to synthesize carbon nanosheets with a yield of above 95%at 500 °C by using ferrocene as catalyst and carbon source and S powder as additive .The results of struc-tural test show that the main products after acid treatment are amorphous carbon nanosheets with a thickness of 40 nm.The results of N 2 adsorption-desorption isotherm indicate the BET surface area of carbon nanosheets is 41.1 m2/g,and the pore-size distribution centered from 3.5 to 5 nm.