焊管
銲管
한관
WELDED PIPE AND TUBE
2014年
10期
11-15
,共5页
申毅%任国琪%王荣
申毅%任國琪%王榮
신의%임국기%왕영
X80管线钢%NS4溶液%动电位极化%波动应力%阳极溶解
X80管線鋼%NS4溶液%動電位極化%波動應力%暘極溶解
X80관선강%NS4용액%동전위겁화%파동응력%양겁용해
X80 pipeline steel%NS4 solution%potentiodynamic polarization%fluctuation stress%anodic dissolution
应用动电位极化方法研究了X80管线钢在不同pH条件下模拟土壤局部环境NS4溶液中的阳极溶解特征,并通过极化曲线的解析得到电化学腐蚀参数。 X80管线钢在NS4溶液中具有活性阳极溶解特征,阳极过程为多步反应机制,局部溶液pH值和波动应力循环对阳极溶解的机制没有影响。当溶液pH值在3~7范围内,随着溶液pH值降低,阳极溶解电流密度增加,波动应力也促进阳极溶解过程。讨论了阳极溶解与管道近中性pH-SCC的关系,可为埋地管道近中性pH-SCC的控制提供参考。
應用動電位極化方法研究瞭X80管線鋼在不同pH條件下模擬土壤跼部環境NS4溶液中的暘極溶解特徵,併通過極化麯線的解析得到電化學腐蝕參數。 X80管線鋼在NS4溶液中具有活性暘極溶解特徵,暘極過程為多步反應機製,跼部溶液pH值和波動應力循環對暘極溶解的機製沒有影響。噹溶液pH值在3~7範圍內,隨著溶液pH值降低,暘極溶解電流密度增加,波動應力也促進暘極溶解過程。討論瞭暘極溶解與管道近中性pH-SCC的關繫,可為埋地管道近中性pH-SCC的控製提供參攷。
응용동전위겁화방법연구료X80관선강재불동pH조건하모의토양국부배경NS4용액중적양겁용해특정,병통과겁화곡선적해석득도전화학부식삼수。 X80관선강재NS4용액중구유활성양겁용해특정,양겁과정위다보반응궤제,국부용액pH치화파동응력순배대양겁용해적궤제몰유영향。당용액pH치재3~7범위내,수착용액pH치강저,양겁용해전류밀도증가,파동응력야촉진양겁용해과정。토론료양겁용해여관도근중성pH-SCC적관계,가위매지관도근중성pH-SCC적공제제공삼고。
Potentiodynamic polarization technique was adopted to investigate the anodic dissolution characteristics of X80 pipeline steel in a simulated localized soil environment,which is NS4 solution. Electrochemical corrosion parameters were obtained by resolving polarization curves. The corrosion of the X80 pipeline steel is characteristic of active anodic dissolution,and the anodic process includes several multi-step reaction mechanisms. The pH-value of the NS4 solution and fluctuation cycle stress have no effect on the mechanism of anodic dissolution. The corrosion current density increases when the value of pH decreases in the range between 3 and 7. Fluctuation stress also enhances the anodic dissolution. The correlation between anodic dissolution and near-neutral pH-SCC was discussed. These can provide a reference for controlling the near-neutral pH-SCC of pipes buried in soil.