北京科技大学学报
北京科技大學學報
북경과기대학학보
JOURNAL OF UNIVERSITY OF SCIENCE AND TECHNOLOGY BEIJING
2014年
11期
1483-1489
,共7页
刘智勇%郑文茹%王力伟%崔中雨%杜翠薇%李晓刚
劉智勇%鄭文茹%王力偉%崔中雨%杜翠薇%李曉剛
류지용%정문여%왕력위%최중우%두취미%리효강
管线%钢腐蚀%土壤%腐蚀特征
管線%鋼腐蝕%土壤%腐蝕特徵
관선%강부식%토양%부식특정
pipelines%steel corrosion%soil%corrosion characteristics
利用矩形剥离缝隙模型研究了库尔勒土壤模拟溶液中 X70管线钢剥离涂层下的滞留液化学特征以及 X70钢腐蚀特征。随着浸泡时间的延长,缝内滞留液的 pH 值逐渐下降直至稳定。 Cl -在缝内滞留液中有不同程度的聚集,其中在缝隙底部的质量浓度最高。 SO2-4的质量浓度在腐蚀初期表现为随距离增加而降低,到腐蚀后期表现为随距离增加而升高。 HCO -3和NO -3的质量浓度从漏点至缝底有小幅降低。阳离子的质量浓度变化不明显。缝内 X70钢的腐蚀形貌表现为明显的点蚀,且随距漏点距离的增加,点蚀越严重。
利用矩形剝離縫隙模型研究瞭庫爾勒土壤模擬溶液中 X70管線鋼剝離塗層下的滯留液化學特徵以及 X70鋼腐蝕特徵。隨著浸泡時間的延長,縫內滯留液的 pH 值逐漸下降直至穩定。 Cl -在縫內滯留液中有不同程度的聚集,其中在縫隙底部的質量濃度最高。 SO2-4的質量濃度在腐蝕初期錶現為隨距離增加而降低,到腐蝕後期錶現為隨距離增加而升高。 HCO -3和NO -3的質量濃度從漏點至縫底有小幅降低。暘離子的質量濃度變化不明顯。縫內 X70鋼的腐蝕形貌錶現為明顯的點蝕,且隨距漏點距離的增加,點蝕越嚴重。
이용구형박리봉극모형연구료고이륵토양모의용액중 X70관선강박리도층하적체류액화학특정이급 X70강부식특정。수착침포시간적연장,봉내체류액적 pH 치축점하강직지은정。 Cl -재봉내체류액중유불동정도적취집,기중재봉극저부적질량농도최고。 SO2-4적질량농도재부식초기표현위수거리증가이강저,도부식후기표현위수거리증가이승고。 HCO -3화NO -3적질량농도종루점지봉저유소폭강저。양리자적질량농도변화불명현。봉내 X70강적부식형모표현위명현적점식,차수거루점거리적증가,점식월엄중。
The chemical characteristics of trapped liquid and the corrosion features of X70 pipeline steel under a disbonded coating in a simulated solution of Kuerle soil were studied by using the rectangular stripping gap model. With the increasing of test time, the pH value of trapped solution gradually declines and finally reaches a stable level. Cl - has different degrees of gathering and its highest concentration occurs in the end of the gap. The concentration of SO2 -4 decreases at the initial stage but increases at the late stage, the concentrations of HCO -3 and NO -3 decrease slightly from the holiday to the end, and the concentration change of cations is not obvious or only a minor reduction. The corrosion morphology of X70 steel under the disbonded coating performs obvious pitting corrosion, which is much more serious with the increasing of distance from the holiday.