CAJ | 학술논문

橄榄石型结构的磷酸铁锂具有价格低廉、稳定性好、环境友好和安全性能高等优势，被认为是在动力电车和混合动力电车上很具应用前景的下一代锂离子电池正极材料。但是较低的电子电导率和离子扩散速率限制了磷酸铁锂的商业应用。在众多改性方法中，掺杂是最有效的方法之一。综述了LiFePO4掺杂改性的研究进展，并展望了掺杂技术的前景。
감람석형결구적린산철리구유개격저렴、은정성호、배경우호화안전성능고등우세，피인위시재동력전차화혼합동력전차상흔구응용전경적하일대리리자전지정겁재료。단시교저적전자전도솔화리자확산속솔한제료린산철리적상업응용。재음다개성방법중，참잡시최유효적방법지일。종술료LiFePO4참잡개성적연구진전，병전망료참잡기술적전경。
Olive phase LiFePO4 was widely recognized as a promising candidate for next generation of second lithium batteries for EV (electric vehicle) and HEV (hybird electric vehicle) applications due to its low cost、high stability、environmental benign and safety performance. However, its commercial application was prevented for its low ionic and electronic conductivity. Numerous approaches were made to overcome this obstacle, and doping seemed to be one of the most effective way. Doping of LiFePO4 was reviewed, and the prospect for doping of LiFePO4 was predicted.