化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2014年
12期
4948-4957
,共10页
唐建业%陈雪莉%乔治%刘爱彬%王辅臣
唐建業%陳雪莉%喬治%劉愛彬%王輔臣
당건업%진설리%교치%류애빈%왕보신
煤%秸秆类生物质%灰熔融特性%矿物质%高温熔融图像
煤%秸稈類生物質%灰鎔融特性%礦物質%高溫鎔融圖像
매%갈간류생물질%회용융특성%광물질%고온용융도상
coal%agro-biomass%ash melting characteristics%mineral matter%high-temperature fusion images
借助高温热台显微镜、扫描电子显微镜-能谱仪、灰熔点仪和 X 射线衍射仪考察了添加稻草和棉秆两种秸秆对长平煤灰熔融特性的影响。研究结果表明添加两种秸秆都能有效地降低长平煤灰的熔融温度。在高温弱还原性气氛下,长平煤灰主要矿物组成为耐熔性石英和莫来石,而添加秸秆后产生了白榴石、尖晶橄榄石、钙长石等低温共熔化合物,使长平煤灰熔点降低。不同灰的高温熔融图像表明,煤灰在熔融过程中由于受热而使固相持续软化,形成了不利于难熔物分解的高黏度熔体。而煤和稻草的混合灰在熔融时形成了易发生流动的低黏度熔体,能够促进矿物质发生反应而更易熔融。
藉助高溫熱檯顯微鏡、掃描電子顯微鏡-能譜儀、灰鎔點儀和 X 射線衍射儀攷察瞭添加稻草和棉稈兩種秸稈對長平煤灰鎔融特性的影響。研究結果錶明添加兩種秸稈都能有效地降低長平煤灰的鎔融溫度。在高溫弱還原性氣氛下,長平煤灰主要礦物組成為耐鎔性石英和莫來石,而添加秸稈後產生瞭白榴石、尖晶橄欖石、鈣長石等低溫共鎔化閤物,使長平煤灰鎔點降低。不同灰的高溫鎔融圖像錶明,煤灰在鎔融過程中由于受熱而使固相持續軟化,形成瞭不利于難鎔物分解的高黏度鎔體。而煤和稻草的混閤灰在鎔融時形成瞭易髮生流動的低黏度鎔體,能夠促進礦物質髮生反應而更易鎔融。
차조고온열태현미경、소묘전자현미경-능보의、회용점의화 X 사선연사의고찰료첨가도초화면간량충갈간대장평매회용융특성적영향。연구결과표명첨가량충갈간도능유효지강저장평매회적용융온도。재고온약환원성기분하,장평매회주요광물조성위내용성석영화막래석,이첨가갈간후산생료백류석、첨정감람석、개장석등저온공용화합물,사장평매회용점강저。불동회적고온용융도상표명,매회재용융과정중유우수열이사고상지속연화,형성료불리우난용물분해적고점도용체。이매화도초적혼합회재용융시형성료역발생류동적저점도용체,능구촉진광물질발생반응이경역용융。
The effects of rice straw (DC) and cotton stalk (MG) addition on Changping (CP) coal ash melting characteristics were studied with high-temperature optical microscopy, scanning electron microscopy coupled with energy dispersive spectrometer (SEM-EDS), standard ash fusion temperature (AFT) tests and X-ray diffraction (XRD) analyses. The AFT of CP coal could be reduced effectively by adding both agricultural residues. In weak reducing atmosphere at high temperature, refractory mullite and quartz were main minerals of CP coal ash. The presence of agricultural residues could form low melting eutectic minerals, such as leucite, ringwoodite and anorthite, decreasing the AFT of CP coal. High temperature images of ash particles showed that CP coal ash fusion behavior was prolonged softening and subsequent melting of solid phases that resulted in sluggish flow and depressed dissolution of the refractory constituents. However, during the melting process of DC blended CP coal ash, active melts with low viscosity that could promote the reaction between the minerals and quickly dissolve the residual refractory were formed.