河海大学学报(自然科学版)
河海大學學報(自然科學版)
하해대학학보(자연과학판)
JOURNAL OF HOHAI UNIVERSITY (NATURAL SCIENCES)
2014年
6期
535-540
,共6页
王卫仑%徐金霞%高国福%蒋林华
王衛崙%徐金霞%高國福%蔣林華
왕위륜%서금하%고국복%장림화
钢筋混凝土结构%电化学除氯%阻锈剂%二%甲基乙醇胺电渗透%联合修复技术
鋼觔混凝土結構%電化學除氯%阻鏽劑%二%甲基乙醇胺電滲透%聯閤脩複技術
강근혼응토결구%전화학제록%조수제%이%갑기을순알전삼투%연합수복기술
reinforced concrete structure%electrochemical chloride removal%corrosion inhibitor%electroosmosis of N,N'-dimethylaminoethanol%combined remediation technology
以二甲基乙醇胺为阻锈剂,通过对比试验,研究电化学除氯法和二甲基乙醇胺电渗透联合修复钢筋的效果及修复后钢筋的腐蚀电化学性能。结果表明:与二甲基乙醇胺阻锈剂的自然渗透和单一的电化学除氯法相比较,联合修复技术具有阻锈剂活性基团渗入更为有效与近似相同去除氯离子的能力;随着通电时间、水灰比的增加,氮元素渗入量和氯离子去除数量增加,而随着外加电压的增加,氮元素渗入量和氯离子去除数量先增加后不变;联合修复处理后砂浆中钢筋有很好的钝化保持能力。
以二甲基乙醇胺為阻鏽劑,通過對比試驗,研究電化學除氯法和二甲基乙醇胺電滲透聯閤脩複鋼觔的效果及脩複後鋼觔的腐蝕電化學性能。結果錶明:與二甲基乙醇胺阻鏽劑的自然滲透和單一的電化學除氯法相比較,聯閤脩複技術具有阻鏽劑活性基糰滲入更為有效與近似相同去除氯離子的能力;隨著通電時間、水灰比的增加,氮元素滲入量和氯離子去除數量增加,而隨著外加電壓的增加,氮元素滲入量和氯離子去除數量先增加後不變;聯閤脩複處理後砂漿中鋼觔有很好的鈍化保持能力。
이이갑기을순알위조수제,통과대비시험,연구전화학제록법화이갑기을순알전삼투연합수복강근적효과급수복후강근적부식전화학성능。결과표명:여이갑기을순알조수제적자연삼투화단일적전화학제록법상비교,연합수복기술구유조수제활성기단삼입경위유효여근사상동거제록리자적능력;수착통전시간、수회비적증가,담원소삼입량화록리자거제수량증가,이수착외가전압적증가,담원소삼입량화록리자거제수량선증가후불변;연합수복처리후사장중강근유흔호적둔화보지능력。
In this study, the effect of remediation of steel reinforcement by combining the electrochemical removal of chloride with electro-migration of N,N'-dimethylaminoethanol and the electrochemical corrosion properties of the steel reinforcement was investigated through a comparative experiment, in which N,N'-dimethylaminoethanol was used as a corrosion inhibitor. The results show that the combined remediation technology can more quickly transport the inhibition groups into the steel reinforcement, and is similarly effective in removing chloride from the steel reinforcement, when compared with the natural diffusion of N, N'-dimethylaminoethanol and the single electrochemical chloride removal method. With the increase of the duration of current and the water-cement ratio, the amounts of nitrogen electro-migrated into the specimens and the chloride removed from the specimens increased. In addition, as the applied voltage increased, the amounts of nitrogen electro-migrated into the specimens and the chloride removed from the specimens initially increased, then remained steadily unchanged. After remediation, the steel reinforcement in the mortar exhibited a strong ability to maintain passivation.