光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
SPECTROSCOPY AND SPECTRAL ANALYSIS
2014年
12期
3374-3379
,共6页
邓春凤%卢彪%伍春雷%汪一夫%温中伟
鄧春鳳%盧彪%伍春雷%汪一伕%溫中偉
산춘봉%로표%오춘뢰%왕일부%온중위
双温度%发射光谱%Culdberg-Waage解离方程%Saha电离方程%准电中性
雙溫度%髮射光譜%Culdberg-Waage解離方程%Saha電離方程%準電中性
쌍온도%발사광보%Culdberg-Waage해리방정%Saha전리방정%준전중성
Two-temperature%Emission spectra%Culdberg-Waage dissociation equation%Saha inoization euqtion%Quasi-nerutal condition
单次脉冲工作的真空弧离子源,采用金属钛吸附氢形成的Ti-H固溶体作阴极,生成的等离子体同时包含金属钛和氢的成分,且在径向、横向以及时间尺度上都存在梯度,整个体系处于非平衡状态,不能用一个统一的温度来描述。假设由电子组成的子系统和由其他重粒子组成的子系统分别达到平衡,即Ti-H等离子体由电子温度和重粒子温度两个温度来描述,为双温度等离子体。采用Culdberg-Waage解离方程和Saha电离方程分别对系统中的分子解离和原子电离过程进行描述,结合等离子体电荷准中性条件,同时引入原子发射光谱这一无干扰的等离子体诊断方法,对 Ti-H 等离子体的温度和粒子数密度进行诊断。在MATLAB环境下,同时考虑金属Ti原子和一价Ti离子的电离,计算结果显示:根据谱线的斯塔克展宽确定的电子密度进行计算,除重粒子温度和氢气分子的数密度之外,其他的参数均可得到较准确的诊断结果;电子密度数值的准确性对计算结果有很大的影响;如果能够在计算之前确定重粒子温度,则可对 Ti-H等离子体的温度和粒子数密度进行准确的定量分析。
單次脈遲工作的真空弧離子源,採用金屬鈦吸附氫形成的Ti-H固溶體作陰極,生成的等離子體同時包含金屬鈦和氫的成分,且在徑嚮、橫嚮以及時間呎度上都存在梯度,整箇體繫處于非平衡狀態,不能用一箇統一的溫度來描述。假設由電子組成的子繫統和由其他重粒子組成的子繫統分彆達到平衡,即Ti-H等離子體由電子溫度和重粒子溫度兩箇溫度來描述,為雙溫度等離子體。採用Culdberg-Waage解離方程和Saha電離方程分彆對繫統中的分子解離和原子電離過程進行描述,結閤等離子體電荷準中性條件,同時引入原子髮射光譜這一無榦擾的等離子體診斷方法,對 Ti-H 等離子體的溫度和粒子數密度進行診斷。在MATLAB環境下,同時攷慮金屬Ti原子和一價Ti離子的電離,計算結果顯示:根據譜線的斯塔剋展寬確定的電子密度進行計算,除重粒子溫度和氫氣分子的數密度之外,其他的參數均可得到較準確的診斷結果;電子密度數值的準確性對計算結果有很大的影響;如果能夠在計算之前確定重粒子溫度,則可對 Ti-H等離子體的溫度和粒子數密度進行準確的定量分析。
단차맥충공작적진공호리자원,채용금속태흡부경형성적Ti-H고용체작음겁,생성적등리자체동시포함금속태화경적성분,차재경향、횡향이급시간척도상도존재제도,정개체계처우비평형상태,불능용일개통일적온도래묘술。가설유전자조성적자계통화유기타중입자조성적자계통분별체도평형,즉Ti-H등리자체유전자온도화중입자온도량개온도래묘술,위쌍온도등리자체。채용Culdberg-Waage해리방정화Saha전리방정분별대계통중적분자해리화원자전리과정진행묘술,결합등리자체전하준중성조건,동시인입원자발사광보저일무간우적등리자체진단방법,대 Ti-H 등리자체적온도화입자수밀도진행진단。재MATLAB배경하,동시고필금속Ti원자화일개Ti리자적전리,계산결과현시:근거보선적사탑극전관학정적전자밀도진행계산,제중입자온도화경기분자적수밀도지외,기타적삼수균가득도교준학적진단결과;전자밀도수치적준학성대계산결과유흔대적영향;여과능구재계산지전학정중입자온도,칙가대 Ti-H등리자체적온도화입자수밀도진행준학적정량분석。
Using the T-H solid solution made by titanium absorbed hydrogen as the cathode ,the Ti-H plasma produced by the pulsed vacuum arc ion source was nonequilibrium :it contained both the component of titanium and hydrogen ;there existed gra-dient in the radiaL ,the horizontal and the time .As a result ,it could not be described by a single temperature .The present paper assumed that the subsystem consisting of electrons and the subsystem consisting of other heavy particles reached equilibrium re-spectively ,meaning that the Ti-H plasma was described by the two temperatures as electron temperature and heavy ion tempera-ture ,it was non-equilibrium two-temperature plasma .Using Culdberg-Waage dissociation equation to describe the molecular dis-sociation process in the system ,using Saha ionization equation to describe the atomic ionization process ,combining plasma’ s charge quasi-neutral condition and introducing atomic emission spectroscopy as a plasma diagnostic method which would not in-terfere the plasma at the same time;the temperature and the particle number density of the Ti-H plasma were diagnosed .Using MATLAB as a tool ,both the titanium atoms and monovalent titanium ions’ ionization were considered ,and the calculated re-sults showed that with the electtron density determined by the Stark broadening of spectral lines in advance ,except the heavy particle temperature and the hydrogen number density ,the Ti-H plasma’s parameters could be diagnosed fairly accurately ;the accuracy of the electron density values had a great effect on the calculation results ;if the heavy particle temperature could be de-termined in advance ,the temperature and the particle number density of the Ti-H plasma could be accurately analyzed quantita-tively .