CAJ | 학술논문

通过介绍人工半导体 Z 反应的原理，综述该类型反应体系，包括模拟 PSI 催化剂（PS1[H2]）、模拟 PSII催化剂（PS2[O2]）和介体（mediator）应用于人工模拟光解水制氢的研究进展，重点阐述此三者在Z反应中所起的作用及其电子传递机理的发展现状，并通过估算不同介体的光能转换效率比较各反应系统的优缺点，指出无介体Z反应系统的电子传递机理、非贵金属助剂的制备、在光催化还原二氧化碳和光电催化中的应用是未来Z反应研究的重点。
통과개소인공반도체 Z 반응적원리，종술해류형반응체계，포괄모의 PSI 최화제（PS1[H2]）、모의 PSII최화제（PS2[O2]）화개체（mediator）응용우인공모의광해수제경적연구진전，중점천술차삼자재Z반응중소기적작용급기전자전체궤리적발전현상，병통과고산불동개체적광능전환효솔비교각반응계통적우결점，지출무개체Z반응계통적전자전체궤리、비귀금속조제적제비、재광최화환원이양화탄화광전최화중적응용시미래Z반응연구적중점。
The principle of artificial semiconductor Z-scheme and recent advance in its catalysts for photocatalytic water splitting for hydrogen production are reviewed,including photosystem I catalysts (PS1[H2]) , photosystem II catalysts (PS2[O2]) and their mediators. Their effects in Z-scheme photocatalysis and mechanism of electron transfer of PS1[H2],PS2[O2] and their mediators are illustrated. A comparison of photo conversion efficiency among some of the reported Z-scheme systems is made. Future research on Z-scheme systems should be focused on the mechanism of electron transfer of Z-scheme systems without mediators,synthesis of non-noble metal co-catalysts and applications in photocatalytic reduction of carbon dioxide and photoelectrochemistry.