发光学报
髮光學報
발광학보
CHINESE JOURNAL OF LUMINESCENCE
2014年
12期
1449-1454
,共6页
杨悦%赵翠真%于晨光%黄枭%吕威
楊悅%趙翠真%于晨光%黃梟%呂威
양열%조취진%우신광%황효%려위
Pt/TiO2%光催化%纳米杯%纳米片
Pt/TiO2%光催化%納米杯%納米片
Pt/TiO2%광최화%납미배%납미편
Pt/TiO2%photocatalysis%nanocup%nanosheet
制备了3种不同形貌的TiO2结构:纳米杯、(001)纳米片、(100)纳米片,并进一步与Pt纳米粒子复合以去除污水中的有机染料。透射电镜结果证实了3种TiO2纳米结构的形成,观察到了附着其上的Pt纳米粒子。使用XRD确定了3种TiO2纳米结构均为锐钛矿相。以罗丹明B作为有机染料,检测了不同形貌TiO2及其Pt复合物的光催化性能。结果表明:纳米杯状的Pt/TiO2在罗丹明B溶液中表现出最高降解率,在1.5 h内降解率可达99.1%。同时讨论了TiO2及其复合物的光降解机理。
製備瞭3種不同形貌的TiO2結構:納米杯、(001)納米片、(100)納米片,併進一步與Pt納米粒子複閤以去除汙水中的有機染料。透射電鏡結果證實瞭3種TiO2納米結構的形成,觀察到瞭附著其上的Pt納米粒子。使用XRD確定瞭3種TiO2納米結構均為銳鈦礦相。以囉丹明B作為有機染料,檢測瞭不同形貌TiO2及其Pt複閤物的光催化性能。結果錶明:納米杯狀的Pt/TiO2在囉丹明B溶液中錶現齣最高降解率,在1.5 h內降解率可達99.1%。同時討論瞭TiO2及其複閤物的光降解機理。
제비료3충불동형모적TiO2결구:납미배、(001)납미편、(100)납미편,병진일보여Pt납미입자복합이거제오수중적유궤염료。투사전경결과증실료3충TiO2납미결구적형성,관찰도료부착기상적Pt납미입자。사용XRD학정료3충TiO2납미결구균위예태광상。이라단명B작위유궤염료,검측료불동형모TiO2급기Pt복합물적광최화성능。결과표명:납미배상적Pt/TiO2재라단명B용액중표현출최고강해솔,재1.5 h내강해솔가체99.1%。동시토론료TiO2급기복합물적광강해궤리。
Pt/TiO2 nanocomposites with three different TiO2 morphologies ( nanocup, ( 001 ) nanosheet, (100) nanosheet) were prepared for removing dye from wastewater. Transmission elec-tron microscopy results confirmed the formation of nanocup, (001) nanosheet, (100) nanosheet of TiO2 and the presence of Pt nanoparticles attached on TiO2 nanostructure. All TiO2 samples are ana-tase indicated by X-ray diffraction. The as-prepared Pt/TiO2 nanocomposites were used as adsorbent to remove dye from wastewater using the organic dye Rhodamine B as adsorbate. The nano-cup Pt/TiO2 sample exhibited the best efficiency on the degradation rate of Rhodamine B, and the removal ratio of the dye gets to 99.1% less than 1. 5 h. Adsorption kinetics and isotherm were investigated and the possible mechanism of the different photocatalytic efficiency was suggested.