CAJ | 학술논문

对具有明显聚集诱导发光性能（AIE）的化合物4，4′－双（2，2′－双（4－（6－（9H－咔唑基）己氧基）苯基）乙烯基）联苯（ p2bc6）以电化学聚合法制备了聚合物发光薄膜。该聚合薄膜的结构、光学性能和表面形貌通过红外光谱、紫外光谱（ UV）、荧光光谱和原子力显微镜表征。结果表明：聚合前体通过分子中咔唑基团聚合形成聚合物薄膜；薄膜具有良好的发光性质；制得的电化学聚合薄膜表面平整，表面粗糙度可达到3 nm以下，有望作为发光材料应用于PLED器件中。
대구유명현취집유도발광성능（AIE）적화합물4，4′－쌍（2，2′－쌍（4－（6－（9H－잡서기）기양기）분기）을희기）련분（ p2bc6）이전화학취합법제비료취합물발광박막。해취합박막적결구、광학성능화표면형모통과홍외광보、자외광보（ UV）、형광광보화원자력현미경표정。결과표명：취합전체통과분자중잡서기단취합형성취합물박막；박막구유량호적발광성질；제득적전화학취합박막표면평정，표면조조도가체도3 nm이하，유망작위발광재료응용우PLED기건중。
A compound ( p2bc6) which shows a significant aggregation-induced emission phenomenon was used to make polymers by electrochemical polymerization.The structures, optical performance and surface morphology of the electrochemical polymerized films were characterized by means of infrared spectroscopy, near ultra violet( UV) , photoluminescence measurements and atomic force microscopy.The results showed that the electrochemical poly-merization proceeded from carbazole groups, the film emitted fluorescence and had flat surface which the root mean square ( rms) of surface roughnesses was less than 3 nm.It is suggested that they are potential materials for fabrica-tion in PLED devices.