功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2012年
7期
924-926,931
,共4页
锂离子电池%硅酸锰锂%多孔球形%正极材料
鋰離子電池%硅痠錳鋰%多孔毬形%正極材料
리리자전지%규산맹리%다공구형%정겁재료
lithium ion batteries%Li2MnSiO4%porous spherical%cathode material
采用湿法球磨-喷雾干燥法制备了多孔球形锂离子电池Li2MnSiO4/C复合正极材料。X射线衍射(XRD)表明合成的Li2MnSiO4具有正交结构,属于Pmn21空间群。扫描电镜(SEM)和透射电镜(TEM)显示粉体复合材料为直径10μm左右的球形团簇,由100nm左右的颗粒堆积而成,颗粒表面包覆1层大约3nm的碳层。电化学测试表明,在0.05和0.5C倍率下,Li2MnSiO4/C样品的首次放电容量分别为153和110mAh/g,50次循环后容量分别保持80%和66%。
採用濕法毬磨-噴霧榦燥法製備瞭多孔毬形鋰離子電池Li2MnSiO4/C複閤正極材料。X射線衍射(XRD)錶明閤成的Li2MnSiO4具有正交結構,屬于Pmn21空間群。掃描電鏡(SEM)和透射電鏡(TEM)顯示粉體複閤材料為直徑10μm左右的毬形糰簇,由100nm左右的顆粒堆積而成,顆粒錶麵包覆1層大約3nm的碳層。電化學測試錶明,在0.05和0.5C倍率下,Li2MnSiO4/C樣品的首次放電容量分彆為153和110mAh/g,50次循環後容量分彆保持80%和66%。
채용습법구마-분무간조법제비료다공구형리리자전지Li2MnSiO4/C복합정겁재료。X사선연사(XRD)표명합성적Li2MnSiO4구유정교결구,속우Pmn21공간군。소묘전경(SEM)화투사전경(TEM)현시분체복합재료위직경10μm좌우적구형단족,유100nm좌우적과립퇴적이성,과립표면포복1층대약3nm적탄층。전화학측시표명,재0.05화0.5C배솔하,Li2MnSiO4/C양품적수차방전용량분별위153화110mAh/g,50차순배후용량분별보지80%화66%。
Porous spherical Li2MnSiO4/C composite was prepared via a wet ball milling-spray drying method and exploited as cathode material for lithium ion batteries.X-ray diffraction(XRD) pattern of the sample conformed the formation of orthorhombic Li2MnSiO4 with Pmn21 space group.The scanning electron microscopy(SEM) and transmission electron microscopy(TEM) showed that the aggregated spherical particles in diameter of 10μm which were composed of large numbers of nanoparticles with size of 100nm.The Li2MnSiO4 nanoparticles were covered with a carbon layer of 3nm thick.The electrochemical test reveale that the initial discharge capacities of Li2MnSiO4/C were 153 and 110mAh/g at 0.05 and 0.5C rate,with the capacity retention of 80% and 66% after 50 cycles,respectively.