功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2012年
14期
1936-1940
,共5页
杨忠莲%高宝玉%王燕%刘新新%岳钦艳
楊忠蓮%高寶玉%王燕%劉新新%嶽欽豔
양충련%고보옥%왕연%류신신%악흠염
复合絮凝剂%生长速度与粒径%差异性%有机组分含量%特性粘度%碱化度
複閤絮凝劑%生長速度與粒徑%差異性%有機組分含量%特性粘度%堿化度
복합서응제%생장속도여립경%차이성%유궤조분함량%특성점도%감화도
composite flocculant%growth rate and size%time-weighted variance%organic component fraction%intrinsic viscosity%basicity
制备出具有不同聚合氯化铁(PFC)碱化度(B)、不同聚环氧氯丙烷-二甲胺(EPI-DMA)质量分数(m(E))和粘度(η)的PFC-EPI-DMA复合混凝剂,对比研究了模拟染料废水絮凝脱色处理中m(E)、η和B对絮体特性的影响。结果表明,处理活性艳红时m(E)值越大,絮体增长速度越快,最终絮体粒度越大,同时絮体差异性增大;处理活性翠兰时,较低投加量下絮体生成速度降低,最终絮体粒度和絮体差异性减小,且较低投加量下,较小的m(E)值有利于絮体快速增长,较高投加量下,较大m(E)值下絮体具有更快的聚集速度、较大的粒径和较小的差异性;η值较高、B值较低时絮凝剂与染料反应时间较短,絮体能以较小的差异更快速地增长。
製備齣具有不同聚閤氯化鐵(PFC)堿化度(B)、不同聚環氧氯丙烷-二甲胺(EPI-DMA)質量分數(m(E))和粘度(η)的PFC-EPI-DMA複閤混凝劑,對比研究瞭模擬染料廢水絮凝脫色處理中m(E)、η和B對絮體特性的影響。結果錶明,處理活性豔紅時m(E)值越大,絮體增長速度越快,最終絮體粒度越大,同時絮體差異性增大;處理活性翠蘭時,較低投加量下絮體生成速度降低,最終絮體粒度和絮體差異性減小,且較低投加量下,較小的m(E)值有利于絮體快速增長,較高投加量下,較大m(E)值下絮體具有更快的聚集速度、較大的粒徑和較小的差異性;η值較高、B值較低時絮凝劑與染料反應時間較短,絮體能以較小的差異更快速地增長。
제비출구유불동취합록화철(PFC)감화도(B)、불동취배양록병완-이갑알(EPI-DMA)질량분수(m(E))화점도(η)적PFC-EPI-DMA복합혼응제,대비연구료모의염료폐수서응탈색처리중m(E)、η화B대서체특성적영향。결과표명,처리활성염홍시m(E)치월대,서체증장속도월쾌,최종서체립도월대,동시서체차이성증대;처리활성취란시,교저투가량하서체생성속도강저,최종서체립도화서체차이성감소,차교저투가량하,교소적m(E)치유리우서체쾌속증장,교고투가량하,교대m(E)치하서체구유경쾌적취집속도、교대적립경화교소적차이성;η치교고、B치교저시서응제여염료반응시간교단,서체능이교소적차이경쾌속지증장。
Polyferric chloride(PFC) and epichlorohydrin-dimethylamine(EPI-DMA) were applied as raw materials to prepare a novel composite inorganic-organic flocculant(PFC-EPI-DMA) with various intrinsic viscosities(η),basicity(B,OH/Fe molar ratio),and organic component fractions(m(E)).The floc characteristics of PFC-EPI-DMA were extensively examined regarding the decolorizing treatment of synthetic active dying wastewater.The effect of B,η and m(E) on the growth rate,size and time-weighted variance(TWV) of formed flocs were also evaluated through photometric dispersion analyzer.Experimental results indicate that higher m(E) was favorable to floc growth rate,floc size and TWV increase when treating active brilliant red.With respect to decolorizing of active blue,the m(E) influence on floc property was related to coagulant dosage.At lower dosage,the floc growth rate,floc size and TWV was reduced.Meanwhile,lower m(E) was beneficial to the more faster aggregation and growth of formed flocs.However,this trend becomes reversed under comparatively higher dosage conditions.In general,composite PFC-EPI-DMA with comparatively higher η and lower B value could obtain larger and more uniform flocs with faster growth rate.