功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2012年
15期
2014-2017,2021
,共5页
羧基离子交换纤维%吸附%电镀废水%镍(Ⅱ)
羧基離子交換纖維%吸附%電鍍廢水%鎳(Ⅱ)
최기리자교환섬유%흡부%전도폐수%얼(Ⅱ)
carboxylic acid ion exchange fiber%adsorption%plating wastewater%nickel( Ⅱ )
系统研究了自制羧基离子交换纤维对电镀废水中Ni 2+的吸附性能。结果表明钠型羧酸纤维的平衡吸附容量远高于相应氢型纤维;静态条件下纤维对Ni 2+的吸附容量可达220mg/g以上;溶液初始浓度、pH值以及温度越高,钠型羧酸纤维的平衡吸附量越大。100~300mg/L范围内的含镍电镀废水经柱吸附后可达国家规定排放浓度(≤0.5mg/L),吸附Ni 2+后的纤维可用2mol/L盐酸溶液解吸,纤维重复使用100次后吸附性能基本不变。
繫統研究瞭自製羧基離子交換纖維對電鍍廢水中Ni 2+的吸附性能。結果錶明鈉型羧痠纖維的平衡吸附容量遠高于相應氫型纖維;靜態條件下纖維對Ni 2+的吸附容量可達220mg/g以上;溶液初始濃度、pH值以及溫度越高,鈉型羧痠纖維的平衡吸附量越大。100~300mg/L範圍內的含鎳電鍍廢水經柱吸附後可達國傢規定排放濃度(≤0.5mg/L),吸附Ni 2+後的纖維可用2mol/L鹽痠溶液解吸,纖維重複使用100次後吸附性能基本不變。
계통연구료자제최기리자교환섬유대전도폐수중Ni 2+적흡부성능。결과표명납형최산섬유적평형흡부용량원고우상응경형섬유;정태조건하섬유대Ni 2+적흡부용량가체220mg/g이상;용액초시농도、pH치이급온도월고,납형최산섬유적평형흡부량월대。100~300mg/L범위내적함얼전도폐수경주흡부후가체국가규정배방농도(≤0.5mg/L),흡부Ni 2+후적섬유가용2mol/L염산용액해흡,섬유중복사용100차후흡부성능기본불변。
The adsorption performance ot carboxylicacid ion exchange ,was studied. The results showed that the adsorption capacity of sodium type carboxylic fiber was much higher than one of the free carboxylic fiber under the same conditions, and the adsorption capacity of sodium type fiber for Ni2+ could be up to 220mg/g. The larger the initial concentration, pH value and temperature of containing nickel solution were, the adsorption capacity of the functional fiber was higher. The CN2+ of filtrate was lower than 0.5mg/L in the column adsorption process when CNi2+ were from 100 mg/ L to 300 mg/ L. The fiber adsorbed Ni2+ could be desorbed by aq. HCl (2mol/ L) , and the adsorption performance of the fiber did not significantly decline after 100 adsorption-desorption cycles.