功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2012年
15期
2052-2055
,共4页
王明光%徐奕辰%祁阳%王志嘉
王明光%徐奕辰%祁暘%王誌嘉
왕명광%서혁신%기양%왕지가
高分辨电子显微镜%取向畴%平移畴界%巨磁阻%薄膜
高分辨電子顯微鏡%取嚮疇%平移疇界%巨磁阻%薄膜
고분변전자현미경%취향주%평이주계%거자조%박막
high-resolution electron microscopy%oriented domain%translational boundary%colossal magnetoresis-tance%film
采用脉冲激光沉积法在LaAlO3(LAO)衬底上生长了YBa2Cu3O7/La0.7Ca0.3MnO3(YBCO/LC-MO)和La0.7Ca0.3MnO3/YBa2Cu3O7(LCMO/YBCO)两种外延薄膜,利用高分辨电子显微镜研究了其微观结构。在YBCO/LCMO/LAO薄膜中,LCMO以层-岛模式生长,并形成层状取向畴结构。YBCO层均由c轴取向晶粒组成,其中含有c/3平移畴界、额外CuO层及Y2O3第二相等缺陷结构。在LCMO/YBCO/LAO薄膜中,LAO衬底上初始生长的YBCO为c轴取向,至一定厚度(几个纳米)转为c与a轴混合生长。LCMO层在YBCO上外延生长并具有[100]m与[011]m混合取向畴结构。在LCMO/YBCO界面未观察到失配位错,因此二者界面属应变型界面。
採用脈遲激光沉積法在LaAlO3(LAO)襯底上生長瞭YBa2Cu3O7/La0.7Ca0.3MnO3(YBCO/LC-MO)和La0.7Ca0.3MnO3/YBa2Cu3O7(LCMO/YBCO)兩種外延薄膜,利用高分辨電子顯微鏡研究瞭其微觀結構。在YBCO/LCMO/LAO薄膜中,LCMO以層-島模式生長,併形成層狀取嚮疇結構。YBCO層均由c軸取嚮晶粒組成,其中含有c/3平移疇界、額外CuO層及Y2O3第二相等缺陷結構。在LCMO/YBCO/LAO薄膜中,LAO襯底上初始生長的YBCO為c軸取嚮,至一定厚度(幾箇納米)轉為c與a軸混閤生長。LCMO層在YBCO上外延生長併具有[100]m與[011]m混閤取嚮疇結構。在LCMO/YBCO界麵未觀察到失配位錯,因此二者界麵屬應變型界麵。
채용맥충격광침적법재LaAlO3(LAO)츤저상생장료YBa2Cu3O7/La0.7Ca0.3MnO3(YBCO/LC-MO)화La0.7Ca0.3MnO3/YBa2Cu3O7(LCMO/YBCO)량충외연박막,이용고분변전자현미경연구료기미관결구。재YBCO/LCMO/LAO박막중,LCMO이층-도모식생장,병형성층상취향주결구。YBCO층균유c축취향정립조성,기중함유c/3평이주계、액외CuO층급Y2O3제이상등결함결구。재LCMO/YBCO/LAO박막중,LAO츤저상초시생장적YBCO위c축취향,지일정후도(궤개납미)전위c여a축혼합생장。LCMO층재YBCO상외연생장병구유[100]m여[011]m혼합취향주결구。재LCMO/YBCO계면미관찰도실배위착,인차이자계면속응변형계면。
Epitaxial YBa2 Cu3O/La0.7 Ca0.3 MnO3 (YBCO/LCMO) and La0.7 Ca0.3 MnO3/YBa2 Cu3 07 ( LCMO/YB-CO) bi-layers were fabricated on LaA103 (LAO) substrate by pulsed laser deposition, and their microstructures were investigated by using high resolution electron microscopy. In YBCO/LCMO/LAO bi-layer, LCMO layer growed on LAO substrate with a layer-island mode, and developed a layered oriented domain structure. YBCO layers consisted of c-axis oriented domain. Some defects such as c/3 translational boundary, extra CuO layer and Y203 second phase were observed in YBCO film. In LCMO/YBCO/LAO hi-layer, the initial YBCO layer on LAO showed c-axis orientation, and switched to a mixed domain structure containing both c-axis and a-axis when the film thickness reached several nanometers. LCMO layer, which comprises a mixed domain of [100]m and [011]m orientation, epitaxially growed on YBCO film. No misfit dislocation was observed between LCMO and YBCO interface, which was characterized by a strain interface.