功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2012年
11期
1498-1502
,共5页
张金艳%林生岭%程小芳%郑海洋
張金豔%林生嶺%程小芳%鄭海洋
장금염%림생령%정소방%정해양
聚苯胺%铁氰化铜%铁氰化铈%铁氰化钴%电化学合成
聚苯胺%鐵氰化銅%鐵氰化鈰%鐵氰化鈷%電化學閤成
취분알%철청화동%철청화시%철청화고%전화학합성
PAni%CuHCF%CoHCF%CeHCF%electropolymerization
以ITO导电玻璃为工作电极,在三电极系统中,采用循环伏安法制得聚苯胺薄膜,聚苯胺/铁氰化铜(CuHCF),聚苯胺/铁氰化钴(CoHCF),聚苯胺/铁氰化铈(CeHCF)复合材料。通过利用C-V、SEM、EDS、XRD、FT-IR等方法对导电复合物进行表征和性能研究。实验结果表明,制备复合物的最佳电解液浓度为0.02mol/L苯胺+0.002mol/L金属离子+0.01mol/L铁氰化钾+0.5mol/L H2SO4;聚苯胺与铁氰化物很好地键合在一起,聚苯胺/铁氰化钴复合材料的电化学性有进一步的提高,具有纳米粒子特性和独特的片状粒子结构;而聚苯胺/铁氰化铜和聚苯胺/铁氰化铈的电化学性能高于聚苯胺本体,粒子间有较大的空穴现象。
以ITO導電玻璃為工作電極,在三電極繫統中,採用循環伏安法製得聚苯胺薄膜,聚苯胺/鐵氰化銅(CuHCF),聚苯胺/鐵氰化鈷(CoHCF),聚苯胺/鐵氰化鈰(CeHCF)複閤材料。通過利用C-V、SEM、EDS、XRD、FT-IR等方法對導電複閤物進行錶徵和性能研究。實驗結果錶明,製備複閤物的最佳電解液濃度為0.02mol/L苯胺+0.002mol/L金屬離子+0.01mol/L鐵氰化鉀+0.5mol/L H2SO4;聚苯胺與鐵氰化物很好地鍵閤在一起,聚苯胺/鐵氰化鈷複閤材料的電化學性有進一步的提高,具有納米粒子特性和獨特的片狀粒子結構;而聚苯胺/鐵氰化銅和聚苯胺/鐵氰化鈰的電化學性能高于聚苯胺本體,粒子間有較大的空穴現象。
이ITO도전파리위공작전겁,재삼전겁계통중,채용순배복안법제득취분알박막,취분알/철청화동(CuHCF),취분알/철청화고(CoHCF),취분알/철청화시(CeHCF)복합재료。통과이용C-V、SEM、EDS、XRD、FT-IR등방법대도전복합물진행표정화성능연구。실험결과표명,제비복합물적최가전해액농도위0.02mol/L분알+0.002mol/L금속리자+0.01mol/L철청화갑+0.5mol/L H2SO4;취분알여철청화물흔호지건합재일기,취분알/철청화고복합재료적전화학성유진일보적제고,구유납미입자특성화독특적편상입자결구;이취분알/철청화동화취분알/철청화시적전화학성능고우취분알본체,입자간유교대적공혈현상。
Polyaniline(PAni),polyaniline/copper hexacyanoferrate(CuHCF) and polyaniline/cobalt hexacyanoferrate(CoHCF),polyaniline/cerium hexacyanoferrate(CeHCF) films were synthesized using the cyclic voltammetry method(C-V) in electrolyte solution.In three electrode systems,the work electrode was the indium-tin-oxide(ITO) glass plate electrode,the electrochemical synthesis potential was in-0.3-1.1V and the scan rate of the system was 50mV/s.And then these films were characterized by C-V,FT-IR,TEM,XRD,EDS.These results showed that the best thickness of electrolyte solution was(0.02mol/L Ani+0.002mol/L metal ion+0.01mol/L K3Fe(CN)6+0.5mol/L H2SO4).Polyaniline and hexacyanoferrate were bonded together,so that the nature of polyaniline/MHCF have further improved.The micromor-phologies of PAni/CoHCF film was schistose and the electrochemical activity was the same as polyaniline.The particle size of PAni/CuHCF and PAni/CeHCF films was nanometer size and there were more cavitations.The electrochemical activity is better than PAni/CoHCF.