功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2012年
15期
2116-2120
,共5页
谢太平%徐龙君%刘成伦%王媛%谢昭明%肖中明
謝太平%徐龍君%劉成倫%王媛%謝昭明%肖中明
사태평%서룡군%류성륜%왕원%사소명%초중명
磁性光催化剂(TiO2-SrFe12O19)%表面性能%磁学性能%光催化降解
磁性光催化劑(TiO2-SrFe12O19)%錶麵性能%磁學性能%光催化降解
자성광최화제(TiO2-SrFe12O19)%표면성능%자학성능%광최화강해
magnetic photocatalyst (TiO2-SrFe12 O19 )%surface properties%magnetic properties%photocatalytic deg-radation
以自制碳酸锶(SrCO3)和钛酸丁酯为原料,采用超声波技术制备了以锶铁氧体(SrFe12O19)为载体的锶磁性光催化剂(TiO2-SrFe12O19)。采用XRD、IR、VSM、N2吸附实验等手段研究了催化剂的表面性质和磁学特性。结果表明,该催化剂的平均晶粒尺寸在20~30nm之间,比表面积为44.8m2/g,平均孔径为7.09nm,属于介孔磁性材料;饱和磁化强度(Ms)为12.9A.m2/kg,矫顽力(Hc)为120.9kA/m,易于磁分离和重复利用。催化剂对亚甲基蓝(MB)的催化降解脱除率为94.7%,且重复使用3次,催化降解效率不低于88%,表明催化性能稳定,重复使用效果良好。
以自製碳痠鍶(SrCO3)和鈦痠丁酯為原料,採用超聲波技術製備瞭以鍶鐵氧體(SrFe12O19)為載體的鍶磁性光催化劑(TiO2-SrFe12O19)。採用XRD、IR、VSM、N2吸附實驗等手段研究瞭催化劑的錶麵性質和磁學特性。結果錶明,該催化劑的平均晶粒呎吋在20~30nm之間,比錶麵積為44.8m2/g,平均孔徑為7.09nm,屬于介孔磁性材料;飽和磁化彊度(Ms)為12.9A.m2/kg,矯頑力(Hc)為120.9kA/m,易于磁分離和重複利用。催化劑對亞甲基藍(MB)的催化降解脫除率為94.7%,且重複使用3次,催化降解效率不低于88%,錶明催化性能穩定,重複使用效果良好。
이자제탄산송(SrCO3)화태산정지위원료,채용초성파기술제비료이송철양체(SrFe12O19)위재체적송자성광최화제(TiO2-SrFe12O19)。채용XRD、IR、VSM、N2흡부실험등수단연구료최화제적표면성질화자학특성。결과표명,해최화제적평균정립척촌재20~30nm지간,비표면적위44.8m2/g,평균공경위7.09nm,속우개공자성재료;포화자화강도(Ms)위12.9A.m2/kg,교완력(Hc)위120.9kA/m,역우자분리화중복이용。최화제대아갑기람(MB)적최화강해탈제솔위94.7%,차중복사용3차,최화강해효솔불저우88%,표명최화성능은정,중복사용효과량호。
Strontium magnetic photocatalyst (TiO2-SrFe12 O19) was prepared from self-made strontium carbonate and tetra-n-butyl titanate by ultrasound technique, when strontium ferrites (SrFe12O19) used as magnetic substrate. Surface properties and magnetic properties of the strontium magnetic photocatalyst were determined by XRD, IR, BET and VSM. The result indicated that the catalyst's the grain size was in the range of 20-30nm, and specific surface area was 44:. 8m2/g, the average pore size was 7.09nm. Therefore,the catalyst was a mesoporous magnetic material. Saturation magnetization 12.9A · m2/kg and 120.9kA/ reuse for this catalyst. TiOe-S tio was 94.7%. The efficient times repeat continuallv. The m, respectively. The hi rFei2 O19 catalyzed the d removal ratio of the ph (Ms) and the eoercivity (He) of the catalyst was gh magnetic property was beneficial to separate easily and egradation reaction of methylene blue (MB), removal raotocatalyst was 88% when the catalyst was employed 3 activity of TiO2-SrFe12 O19 was stable in the process of pollutant degradation.