功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2012年
17期
2283-2285,2290
,共4页
纳米隔热材料%导热系数%尺寸效应
納米隔熱材料%導熱繫數%呎吋效應
납미격열재료%도열계수%척촌효응
nano insulations%thermal conductivity%size effect
纳米隔热材料具有优良的隔热性能,在高超声速飞行器热防护技术中有着广泛应用前景。针对纳米隔热材料固体构架导热系数的尺寸效应,基于声子辐射传输方程建立了声子导热的二维计算模型,采用离散坐标法进行数值计算,以SiO2二维纳米链为例,对其横向及纵向导热系数尺寸效应进行了数值模拟。模拟结果表明,SiO2纳米隔热材料的二维纳米链导热具有明显尺寸效应,导热系数主要受纳米链直径影响,对直径2~4nm的纳米链,其导热系数比块材的导热系数小15%以上,研究结果对认识纳米隔热材料内固体构架热量传递机理具有一定指导作用。
納米隔熱材料具有優良的隔熱性能,在高超聲速飛行器熱防護技術中有著廣汎應用前景。針對納米隔熱材料固體構架導熱繫數的呎吋效應,基于聲子輻射傳輸方程建立瞭聲子導熱的二維計算模型,採用離散坐標法進行數值計算,以SiO2二維納米鏈為例,對其橫嚮及縱嚮導熱繫數呎吋效應進行瞭數值模擬。模擬結果錶明,SiO2納米隔熱材料的二維納米鏈導熱具有明顯呎吋效應,導熱繫數主要受納米鏈直徑影響,對直徑2~4nm的納米鏈,其導熱繫數比塊材的導熱繫數小15%以上,研究結果對認識納米隔熱材料內固體構架熱量傳遞機理具有一定指導作用。
납미격열재료구유우량적격열성능,재고초성속비행기열방호기술중유착엄범응용전경。침대납미격열재료고체구가도열계수적척촌효응,기우성자복사전수방정건립료성자도열적이유계산모형,채용리산좌표법진행수치계산,이SiO2이유납미련위례,대기횡향급종향도열계수척촌효응진행료수치모의。모의결과표명,SiO2납미격열재료적이유납미련도열구유명현척촌효응,도열계수주요수납미련직경영향,대직경2~4nm적납미련,기도열계수비괴재적도열계수소15%이상,연구결과대인식납미격열재료내고체구가열량전체궤리구유일정지도작용。
Nano insulations have excellent insulating performance and find wide application in hypersonic vehicle thermal protection technologies.In this study a two dimensional computational model based upon phonon radiative transfer equation for phonon transport in the solid of nano insulations was established.The discrete ordinate method was used to solve the transport equation numerically.The size effects in the longitudinal and transverse conductivity were numerically simulated for a 2D silica nanowire.Results showed that obvious size effect in the conductivity exists in the 2D nanowire and the conductivity was mainly influenced by the wire diameter.For the nanowire with the diameter between 2-4nm considered,its thermal conductivity was 15% less than the bulk material.Results obtained in this study may be useful in recognizing the heat transfer mechanism in solids of nano insulations.