功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2012年
17期
2416-2420
,共5页
唐艳军%刘晓峰%夏军%薛国新%王进
唐豔軍%劉曉峰%夏軍%薛國新%王進
당염군%류효봉%하군%설국신%왕진
纳米TiO2%壳聚糖%涂料%抗菌纸%抗菌效率
納米TiO2%殼聚糖%塗料%抗菌紙%抗菌效率
납미TiO2%각취당%도료%항균지%항균효솔
nanosized TiO2%chitosan%paper coatings%antimicrobial paper%antimicrobial activity
以纳米TiO2、壳聚糖双胍盐酸盐为抗菌剂,加以胶黏剂羧基丁苯胶乳、分散剂六偏磷酸钠、消泡剂叔丁醇,制备了TiO2/壳聚糖纳米复合涂料,利用SEM、FT-IR对涂料的微观形貌和基本结构进行了表征。以表面涂布方式将TiO2/壳聚糖纳米复合涂料施涂于纸张表面,制得涂布抗菌纸,对涂布抗菌纸的微观结构及抗菌性能进行了研究。结果表明,经TiO2/壳聚糖纳米复合涂料涂布后,纸张具备较强的抗菌性能;而且,实验发现,随着涂料体系中壳聚糖组分的不断增加,涂布纸的抗菌性能逐渐提高。当纳米TiO2/壳聚糖的加入比例为1∶1时,双层涂布后的纸张对大肠杆菌和金黄色葡萄球菌的抗菌率分别达到86.55%和92.19%。
以納米TiO2、殼聚糖雙胍鹽痠鹽為抗菌劑,加以膠黏劑羧基丁苯膠乳、分散劑六偏燐痠鈉、消泡劑叔丁醇,製備瞭TiO2/殼聚糖納米複閤塗料,利用SEM、FT-IR對塗料的微觀形貌和基本結構進行瞭錶徵。以錶麵塗佈方式將TiO2/殼聚糖納米複閤塗料施塗于紙張錶麵,製得塗佈抗菌紙,對塗佈抗菌紙的微觀結構及抗菌性能進行瞭研究。結果錶明,經TiO2/殼聚糖納米複閤塗料塗佈後,紙張具備較彊的抗菌性能;而且,實驗髮現,隨著塗料體繫中殼聚糖組分的不斷增加,塗佈紙的抗菌性能逐漸提高。噹納米TiO2/殼聚糖的加入比例為1∶1時,雙層塗佈後的紙張對大腸桿菌和金黃色葡萄毬菌的抗菌率分彆達到86.55%和92.19%。
이납미TiO2、각취당쌍고염산염위항균제,가이효점제최기정분효유、분산제륙편린산납、소포제숙정순,제비료TiO2/각취당납미복합도료,이용SEM、FT-IR대도료적미관형모화기본결구진행료표정。이표면도포방식장TiO2/각취당납미복합도료시도우지장표면,제득도포항균지,대도포항균지적미관결구급항균성능진행료연구。결과표명,경TiO2/각취당납미복합도료도포후,지장구비교강적항균성능;이차,실험발현,수착도료체계중각취당조분적불단증가,도포지적항균성능축점제고。당납미TiO2/각취당적가입비례위1∶1시,쌍층도포후적지장대대장간균화금황색포도구균적항균솔분별체도86.55%화92.19%。
TiO2/chitosan nanocomposited coatings was prepared by the combination of nanosized TiO2,chitosan biguanidine hydrochloride,SBR latex and other additives.The surface structure of TiO2/chitosan nanocomposited coating samples was characterized by SEM and FT-IR techniques.A new method of antibacterial coated paper based on the TiO2/chitosan nanocomposited coatings was carried out,and the microstructure and antibacterial properties of coated paper was characterized.It was shown that there was a significant increase in antibacterial properties when the paper was coated by TiO2/chitosan nanocomposited coatings.It was especially illustrated that with the increase of chitosan biguanidine hydrochloride amount in paper coatings,the antibacterial properties of coated paper can be persistently improved.When the proportion of TiO2,chitosan in nanocomposited coatings was equal,the antibacterial efficiency of coated paper to escherichia coli and staphylococcus aureus could attain to 86.55% and 92.19%,respectively.