CAJ | 학술논문

采用共沉淀法在700℃和较短的烧结时间下制备了Zn3（BO3）2和不同浓度的Ce3＋、Mn2＋离子掺杂的Zn3（BO3）2纳米晶粉末,对合成产物的发光性质及发光机理进行了研究。利用荧光分光光度计、X射线粉末衍射仪以及透射电镜对其光学性能和纳米晶形貌进行了表征。结果表明Ce3＋离子掺杂的Zn3（BO3）2样品在340～400nm之间有强的荧光发射,其最高发射峰峰位为365nm,在Ce3＋掺量为0.5%（摩尔分数,下同）时发光强度达到最高值。Ce3＋取代Zn2＋离子作为发光中心,Mn2＋离子作为激活剂加入,并不影响荧光发射峰的位置,但能够有效增强其发光强度。当Mn2＋离子掺量为0.7%（摩尔分数）时,Ce3＋、Mn2＋共掺杂的Zn3（BO3）2纳米晶发光强度达到最高值。
채용공침정법재700℃화교단적소결시간하제비료Zn3（BO3）2화불동농도적Ce3＋、Mn2＋리자참잡적Zn3（BO3）2납미정분말,대합성산물적발광성질급발광궤리진행료연구。이용형광분광광도계、X사선분말연사의이급투사전경대기광학성능화납미정형모진행료표정。결과표명Ce3＋리자참잡적Zn3（BO3）2양품재340～400nm지간유강적형광발사,기최고발사봉봉위위365nm,재Ce3＋참량위0.5%（마이분수,하동）시발광강도체도최고치。Ce3＋취대Zn2＋리자작위발광중심,Mn2＋리자작위격활제가입,병불영향형광발사봉적위치,단능구유효증강기발광강도。당Mn2＋리자참량위0.7%（마이분수）시,Ce3＋、Mn2＋공참잡적Zn3（BO3）2납미정발광강도체도최고치。
The Zn3 （BO3）2 nanocrystals and the Zn2 （BO3）2 samples doped with different mole fraction of Ce3＋ and Mn2＋ were prepared by co-precipitate method at 700℃ and under a short sintering time. The luminescent properties and morphologies of products were investigated by fluorospectrophotometer, X-ray diffractometer, and transmission electron microscope. The results indicate that the Ce^3＋-doped samples （Zn3 （BO3）2 ： Ce^3＋） exhibit strong emission from 340 to 400nm. Furthermore, the luminescent intensity of the Zn3 （BO3）2 ： Ce^3＋ sample doped with 0.5 % in mole Ce^3＋ reaches the maximum value. The Ce^3＋ ions substituted for Zn^2＋ in the host and acted as emission centers, and Mn^2＋ acted as activator. The position of the emission peak was unchanged, but the emission intensity of Ce^2＋ , Mn^2＋ co-doped samples was changed obviously with the addition of Ce^3＋. The luminescent intensity of the Zn3 （BO3）2 samples doped with 0.5 % in mole Ce^3＋ and 0.7% in mole Mn^2＋ reaches the maximum value.