功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2012年
22期
3101-3105
,共5页
程绍玲%杨迎花%梁峰杰%魏树梅
程紹玲%楊迎花%樑峰傑%魏樹梅
정소령%양영화%량봉걸%위수매
磁性%分子印迹聚合物%氨基酸%模板%吸附
磁性%分子印跡聚閤物%氨基痠%模闆%吸附
자성%분자인적취합물%안기산%모판%흡부
magnetic%molecularly imprinted polymer%amino acid%templates%adsorption
采用分子印迹技术,以Ala和Phe为模板分子,苯乙烯和甲基丙烯酸为共聚单体,二乙烯苯为交联剂,Fe3O4为磁性载体,制备了对两种氨基酸有特异性识别的磁性分子印迹聚合物Ala-MMIPs和Phe-MMIPs。研究了两种印迹聚合物的吸附特性,并探讨了吸附机理。结果表明,Phe在其印迹聚合物上的最大吸附量和吸附平衡常数分别为231.62μmol/g和0.21L/mmol;而Ala在它的印迹微球上的最大吸附量和吸附平衡常数分别为179.16μmol/g和0.12L/mmol。说明Phe与Phe-MMIPs有3个作用位点,Ala与Ala-MMIPs之间有2个作用位点,因此吸附能力前者大于后者。
採用分子印跡技術,以Ala和Phe為模闆分子,苯乙烯和甲基丙烯痠為共聚單體,二乙烯苯為交聯劑,Fe3O4為磁性載體,製備瞭對兩種氨基痠有特異性識彆的磁性分子印跡聚閤物Ala-MMIPs和Phe-MMIPs。研究瞭兩種印跡聚閤物的吸附特性,併探討瞭吸附機理。結果錶明,Phe在其印跡聚閤物上的最大吸附量和吸附平衡常數分彆為231.62μmol/g和0.21L/mmol;而Ala在它的印跡微毬上的最大吸附量和吸附平衡常數分彆為179.16μmol/g和0.12L/mmol。說明Phe與Phe-MMIPs有3箇作用位點,Ala與Ala-MMIPs之間有2箇作用位點,因此吸附能力前者大于後者。
채용분자인적기술,이Ala화Phe위모판분자,분을희화갑기병희산위공취단체,이을희분위교련제,Fe3O4위자성재체,제비료대량충안기산유특이성식별적자성분자인적취합물Ala-MMIPs화Phe-MMIPs。연구료량충인적취합물적흡부특성,병탐토료흡부궤리。결과표명,Phe재기인적취합물상적최대흡부량화흡부평형상수분별위231.62μmol/g화0.21L/mmol;이Ala재타적인적미구상적최대흡부량화흡부평형상수분별위179.16μmol/g화0.12L/mmol。설명Phe여Phe-MMIPs유3개작용위점,Ala여Ala-MMIPs지간유2개작용위점,인차흡부능력전자대우후자。
Two amino acids magnetic molecularly imprinted polymers, Ala-MMIPs and Phe-MMIPs were prepared by using Ata and Phe as template molecules, styrene and methacrylic acid as functional monomers, divinylbenzene as cross-linking agent and Fe3O4 as magnetic fluid. Adsorption properties of these two imprinted polymers were researched. Adsorption mechanism was also discussed. The maximum adsorption capacity (qmax) and the adsorption equilibrium constant (K) of Phe on Phe-MMIPs were 231. 62μmol/g and 0. 21L/ mmol respectively. The maximum adsorption capacity and the adsorption equilibrium constant of Ala on AlaMMIPs were 179. 16μmol/g and 0. 12L/mmol respectively. The results exhibit that three site interaction between Phe and Phe-MMIPs was stronger than the two-site interaction between Ala and Ala-MMIPs.