功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2012年
10期
1323-1326,1331
,共5页
赫丽杰%张冬%冯守华%陈岗%邹勃
赫麗傑%張鼕%馮守華%陳崗%鄒勃
혁려걸%장동%풍수화%진강%추발
水热合成%钙钛矿结构%光催化性质
水熱閤成%鈣鈦礦結構%光催化性質
수열합성%개태광결구%광최화성질
hydrothermal synthesis%perovskite structure%photocatalyst
采用水热法制备了钙钛矿型化合物Ag-NbO3晶体,对化合物进行粉末X射线表征。Rietveld精修结果表明化合物AgNbO3属于三方晶系,空间群为R-3C。并对化合物进行了扫描电子显微镜(SEM)、BET法测定比表面积和对固体紫外漫反射光谱进行表征。对该化合物的光催化性质进行了测试,在可见光照射下降解染料龙胆紫。结果表明此化合物在室温下具有很高的光催化性质,在光催化性能方面具有潜在的应用价值。
採用水熱法製備瞭鈣鈦礦型化閤物Ag-NbO3晶體,對化閤物進行粉末X射線錶徵。Rietveld精脩結果錶明化閤物AgNbO3屬于三方晶繫,空間群為R-3C。併對化閤物進行瞭掃描電子顯微鏡(SEM)、BET法測定比錶麵積和對固體紫外漫反射光譜進行錶徵。對該化閤物的光催化性質進行瞭測試,在可見光照射下降解染料龍膽紫。結果錶明此化閤物在室溫下具有很高的光催化性質,在光催化性能方麵具有潛在的應用價值。
채용수열법제비료개태광형화합물Ag-NbO3정체,대화합물진행분말X사선표정。Rietveld정수결과표명화합물AgNbO3속우삼방정계,공간군위R-3C。병대화합물진행료소묘전자현미경(SEM)、BET법측정비표면적화대고체자외만반사광보진행표정。대해화합물적광최화성질진행료측시,재가견광조사하강해염료룡담자。결과표명차화합물재실온하구유흔고적광최화성질,재광최화성능방면구유잠재적응용개치。
The perovskite-type AgNbO3 crystals was prepared by mild hydrothermal method and determined by powder X-ray diffraction. Rietveld refinements indicate that AgNbO3 crystallize in trigonal system with space group R-3C. The compounds were characterized by scanning electron microscopy (SEM), brunauer-emmet-tell- er surface area (BET), XPS, FT-IR and UV-Vis diffuse reflectance spectra (UV-Vis DRS). The photocatalytic activity of AgNbO3 powders were evaluated by degradation of gentian violet under visible-light irradiation. The results show that the titled compounds have high photocatalytic activity at room temperature and potential fu- ture applications in photocatalysis.