功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2012年
11期
1443-1445,1449
,共4页
射频磁控溅射%TiO2薄膜%椭圆偏振技术%光学性能
射頻磁控濺射%TiO2薄膜%橢圓偏振技術%光學性能
사빈자공천사%TiO2박막%타원편진기술%광학성능
radio-frequency magnetron sputtering%TiO2 thin films%spectroscopic ellipsometry%optical properties
在硅片和石英上利用射频溅射法沉积了TiO2薄膜,并分别在空气中进行了退火处理。利用椭偏光谱仪对硅片上薄膜进行了椭偏测试,利用紫外-可见分光光度计对石英上薄膜进行了透射光谱测试。利用解谱软件对椭偏谱和透射谱进行了建模解谱,获得了不同基片上薄膜在不同退火温度下的折射指数和消光系数,发现和TiO2块材的光学常数也有明显的区别。通过计算得到了系列薄膜的光学带隙,带隙值范围从3.35~3.88eV,可以为薄膜态TiO2体系的光学应用、设计和相关理论研究提供一定的依据。
在硅片和石英上利用射頻濺射法沉積瞭TiO2薄膜,併分彆在空氣中進行瞭退火處理。利用橢偏光譜儀對硅片上薄膜進行瞭橢偏測試,利用紫外-可見分光光度計對石英上薄膜進行瞭透射光譜測試。利用解譜軟件對橢偏譜和透射譜進行瞭建模解譜,穫得瞭不同基片上薄膜在不同退火溫度下的摺射指數和消光繫數,髮現和TiO2塊材的光學常數也有明顯的區彆。通過計算得到瞭繫列薄膜的光學帶隙,帶隙值範圍從3.35~3.88eV,可以為薄膜態TiO2體繫的光學應用、設計和相關理論研究提供一定的依據。
재규편화석영상이용사빈천사법침적료TiO2박막,병분별재공기중진행료퇴화처리。이용타편광보의대규편상박막진행료타편측시,이용자외-가견분광광도계대석영상박막진행료투사광보측시。이용해보연건대타편보화투사보진행료건모해보,획득료불동기편상박막재불동퇴화온도하적절사지수화소광계수,발현화TiO2괴재적광학상수야유명현적구별。통과계산득도료계렬박막적광학대극,대극치범위종3.35~3.88eV,가이위박막태TiO2체계적광학응용、설계화상관이론연구제공일정적의거。
TiO2 thin films were deposited on Si and quartz substrates via radio-frequency magnetron sputtering and post annealed at different temperatures in atmosphere.The transmittance of the films deposited on quartz and ellipsometric spectra of the films on Si were obtained by UV-Vis spectrophotometer and spectroscopic ellipsometer,respectively.The optical constants of the films deposited on different substrates were extracted by fitting the transmittance and ellipsometric spectra,and were found obviously different from those of TiO2 bulk material.The band gaps of the films were also determined and the values vary from 3.35 to 3.88eV.Our results would be helpful for the design and application of TiO2 filmsystem and related theoretical studies.