功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2012年
21期
2942-2945
,共4页
铁基纳米晶%腐蚀%软磁性能
鐵基納米晶%腐蝕%軟磁性能
철기납미정%부식%연자성능
Fe-based nanoerystalline%corrosion%soft magnetic properties
研究了Fe73.5Cu1Nb3Si13.5B9纳米晶合金在0.1mol/L的NaCl溶液中的耐腐蚀性能,及对其软磁性能的影响。实验结果表明,Fe73.5Cu1Nb3Si13.5B9纳米晶合金经0.1mol/L的NaCl溶液腐蚀后溶液中有橙色沉淀物产生,XRD测试表明铁基纳米晶合金腐蚀后仍保留非晶纳米晶双相结构;铁基纳米晶合金有效磁导率口。随腐蚀时间的增加而降低,腐蚀30d后在频率为50Hz、1、100kHz时其有效磁导率μc较腐蚀前分别下降35.9%、35.3%、27.6%,矫顽力Hc由腐蚀前的0.7097A/m增加到1.117A/m,增加了57.4%,磁滞损耗Pu由腐蚀前的1.819J/m^3增加到2.994J/m^3,增加了64.6%,腐蚀后铁基纳米晶合金软磁性能有所下降。
研究瞭Fe73.5Cu1Nb3Si13.5B9納米晶閤金在0.1mol/L的NaCl溶液中的耐腐蝕性能,及對其軟磁性能的影響。實驗結果錶明,Fe73.5Cu1Nb3Si13.5B9納米晶閤金經0.1mol/L的NaCl溶液腐蝕後溶液中有橙色沉澱物產生,XRD測試錶明鐵基納米晶閤金腐蝕後仍保留非晶納米晶雙相結構;鐵基納米晶閤金有效磁導率口。隨腐蝕時間的增加而降低,腐蝕30d後在頻率為50Hz、1、100kHz時其有效磁導率μc較腐蝕前分彆下降35.9%、35.3%、27.6%,矯頑力Hc由腐蝕前的0.7097A/m增加到1.117A/m,增加瞭57.4%,磁滯損耗Pu由腐蝕前的1.819J/m^3增加到2.994J/m^3,增加瞭64.6%,腐蝕後鐵基納米晶閤金軟磁性能有所下降。
연구료Fe73.5Cu1Nb3Si13.5B9납미정합금재0.1mol/L적NaCl용액중적내부식성능,급대기연자성능적영향。실험결과표명,Fe73.5Cu1Nb3Si13.5B9납미정합금경0.1mol/L적NaCl용액부식후용액중유등색침정물산생,XRD측시표명철기납미정합금부식후잉보류비정납미정쌍상결구;철기납미정합금유효자도솔구。수부식시간적증가이강저,부식30d후재빈솔위50Hz、1、100kHz시기유효자도솔μc교부식전분별하강35.9%、35.3%、27.6%,교완력Hc유부식전적0.7097A/m증가도1.117A/m,증가료57.4%,자체손모Pu유부식전적1.819J/m^3증가도2.994J/m^3,증가료64.6%,부식후철기납미정합금연자성능유소하강。
The corrosion resistance of Fe73. sCu1Nb3Si13.5B9 nanocrystalline alloys in 0. 1mol/L NaCl solution and its influence to soft magnetic properties were studied. The results show that an orange precipitate was produced in the NaCl solution after corrosion, X-ray diffraction show that Fe-based nanocrystalline alloys retain amorphous-nanocrystalline duplex structure after corrosion; the effective permeability of Fe-based nanocrystalline alloys reduce with increasing of corrosion time, after corrosion for 30d, the effective permeability decreased by 35.9%, 35. 3% and 27. 6% at 50Hz, 1 and 100kHz, respectively, coercive force increase from 0. 7097 to 1.117A/m, increased by 57.4%, hysteresis loss increase from 1. 819 to 2. 994J/m^3 , increased by 64.6%, the soft magnetic properties of Fe-based nanocrystalline alloys are decreased after corrosion.