CAJ | 학술논문

以CdCl2和TeO2为原料,硼氢化钠为还原剂,采用水相合成法制备巯基丁二酸稳定CdTe量子点。研究了反应时间、碲和镉的物质的量之比等实验条件对CdTe量子点发光性能的影响,并用X射线粉末衍射、透射电镜、红外光谱、紫外-可见吸收光谱和荧光光谱等分析技术对其进行表征。实验表明,合成的量子点为立方晶型,颗粒大小分布均匀。反应时间及碲和镉的物质的量之比对量子点的发光性能有明显影响,随着反应时间的延长,量子点的吸收与荧光光谱都向长波方向移动,在pH值为10.5的碱性条件下,当n（Cd）∶n（Te）∶n（MSA）=1∶0.05∶1.4时,在5h的时间内可获得发绿色到红色荧光的量子点,最高荧光量子产率为70.3%。
이CdCl2화TeO2위원료,붕경화납위환원제,채용수상합성법제비구기정이산은정CdTe양자점。연구료반응시간、제화력적물질적량지비등실험조건대CdTe양자점발광성능적영향,병용X사선분말연사、투사전경、홍외광보、자외-가견흡수광보화형광광보등분석기술대기진행표정。실험표명,합성적양자점위립방정형,과립대소분포균균。반응시간급제화력적물질적량지비대양자점적발광성능유명현영향,수착반응시간적연장,양자점적흡수여형광광보도향장파방향이동,재pH치위10.5적감성조건하,당n（Cd）∶n（Te）∶n（MSA）=1∶0.05∶1.4시,재5h적시간내가획득발록색도홍색형광적양자점,최고형광양자산솔위70.3%。
Mercaptosuccinic acid(MSA)-capped CdTe quantum dots(QDs) were prepared in an aqueous medium with CdCl2 and TeO2 as raw materials,and NaBH4 as reductant.The influence of refluxing time and tellurium to cadmium molar ratio on the luminescent properties of the obtained CdTe QDs were investigated,and the obtained QDs were characterized by X-ray powder diffraction(XRD),transmission electron microscopy(TEM),Fourier transform infrared spectroscopy(FT-IR),ultraviolet-visible spectroscopy and fluorescent spectroscopy,respectively.The results showed that the CdTe QDs were of zinc-blended crystal structure in a sphere-like shape.The absorption and fluorescence spectra of QDs shifted to longer wavelengths with the increasing of refluxing time.The CdTe QDs with the emission color ranging from green to red could be prepared at pH=10.5,n(Cd)∶n(Te)∶n(MSA)=1∶0.05∶1.4 within 5h,the maximum quantum yield was 70.3%.