CAJ | 학술논문

在3L的高压磁力搅拌釜中通过催化胺化三官能团聚醚多元醇,研究了活化后雷尼镍催化剂的组成对反应的影响。实验结果表明,端氨基聚醚合成反应催化剂的铝含量约为20%（质量分数）时活性较高,产品的总胺值可以达到340mg KOH/g,这与传统雷尼镍催化剂的铝含量（〈10%（质量分数））不同。应用X射线衍射（XRD）对催化剂进行了表征,其化学组成则用等离子体发射光谱仪（ICP-AES）进行分析。反应原料、中间产物、胺化产物用傅立叶变换红外光谱（FT-IR）进行分析,反应原料、产物和尾气用气相色谱（GC）进行分析,并推测了反应路线。
재3L적고압자력교반부중통과최화알화삼관능단취미다원순,연구료활화후뢰니얼최화제적조성대반응적영향。실험결과표명,단안기취미합성반응최화제적려함량약위20%（질량분수）시활성교고,산품적총알치가이체도340mg KOH/g,저여전통뢰니얼최화제적려함량（〈10%（질량분수））불동。응용X사선연사（XRD）대최화제진행료표정,기화학조성칙용등리자체발사광보의（ICP-AES）진행분석。반응원료、중간산물、알화산물용부립협변환홍외광보（FT-IR）진행분석,반응원료、산물화미기용기상색보（GC）진행분석,병추측료반응로선。
The effect of the activated Raney nickel catalyst composition on the catalytic amination was studied by preparation of trifunctional amine terminated polyether in a magnetically stirred stainless steel autoclave.The experiments indicated that the catalyst with 20% aluminium was more effective for the catalytic amination of polyether polyols,and the total amine of the product was up to 340mg KOH/g.X-ray diffraction(XRD) was employed to characterize the catalyst properties and the chemical composition was analyzed by inductively coupled plasma-atomic emission spectrometry(ICP-AES).The reaction route was deduced on the basis of the products and the off-gas analysis by gas chromatography(GC) and fourier transform infrared spectroscopy(FT-IR).