CAJ | 학술논문

以AuCu3-亚格子系统为例，介绍3项发现：第一，迄今阻碍金属材料科学进步的第三大障碍是研究者们习惯用平衡均匀转变的思维方式认识温度极其缓慢变化的合金相变实验现象，然后以实验现象的错误认识为选择信息，建立 Gibbs 能函数和所谓的“平衡相图”；第二，AuCu3-型亚格子系统的平衡全息网络相图可用来描述与成分和温度有关的合金基因排列结构和各种热力学性质的系统相关性；第三，每个合金的平衡转变都是均匀的单相转变，不是非均匀的双相转变，存在一条没有有序相和无序相共存区的单相相界线，相界线顶点成分和温度远偏离AuCu3化合物临界点的计量成分和温度。
이AuCu3-아격자계통위례，개소3항발현：제일，흘금조애금속재료과학진보적제삼대장애시연구자문습관용평형균균전변적사유방식인식온도겁기완만변화적합금상변실험현상，연후이실험현상적착오인식위선택신식，건립 Gibbs 능함수화소위적“평형상도”；제이，AuCu3-형아격자계통적평형전식망락상도가용래묘술여성분화온도유관적합금기인배렬결구화각충열역학성질적계통상관성；제삼，매개합금적평형전변도시균균적단상전변，불시비균균적쌍상전변，존재일조몰유유서상화무서상공존구적단상상계선，상계선정점성분화온도원편리AuCu3화합물림계점적계량성분화온도。
Taking AuCu3-type sublattice system as an example, three discoveries have been presented: First, the third barrier hindering the progress in metal materials science is that researchers have got used to recognizing experimental phenomena of alloy phase transitions during extremely slow variation in temperature by equilibrium thinking mode and then taking erroneous knowledge of experimental phenomena as selected information for establishing Gibbs energy function and so-called equilibrium phase diagram. Second, the equilibrium holographic network phase diagrams of AuCu3-type sublattice system may be used to describe systematic correlativity of the composition?temperature-dependent alloy gene arranging structures and complete thermodynamic properties, and to be a standard for studying experimental subequilibrium order-disorder transition. Third, the equilibrium transition of each alloy is a homogeneous single-phase rather than a heterogeneous two-phase, and there exists a single-phase boundary curve without two-phase region of the ordered and disordered phases; the composition and temperature of the top point on the phase-boundary curve are far away from the ones of the critical point of the AuCu3 compound.