中国有色金属学报(英文版)
中國有色金屬學報(英文版)
중국유색금속학보(영문판)
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
2014年
11期
3492-3499
,共8页
刘娜%李周%李灵%刘斌%徐根应
劉娜%李週%李靈%劉斌%徐根應
류나%리주%리령%류빈%서근응
无镍白色铜合金%热压缩变形%本构方程%加工图
無鎳白色銅閤金%熱壓縮變形%本構方程%加工圖
무얼백색동합금%열압축변형%본구방정%가공도
Ni-free white copper alloy%hot compression deformation%constitutive equation%processing map
采用Gleeble?1500热模拟实验机在温度为600~800°C、应变速率为0.01~10 s?1的热变形条件下对新型无镍白色Cu?12Mn?15Zn?1.5Al?0.3Ti?0.14B?0.1Ce(质量分数,%)合金进行热压缩模拟实验;根据该合金热变形行为及热加工特征,建立该合金热变形的本构方程和热加工图。该合金热变形过程中变形激活能为203.005 kJ/mol。当真应变为0.7时,合金热加工图中存在一个失稳区,此区域的变形温度为600~700°C,应变速率为0.32~10 s?1。在较适宜的热变形条件(800°C、10 s?1)下获得的合金具有良好的表面质量和内部组织。同时,该无镍合金具有与传统镍白铜Cu?15Ni?24Zn?1.5Pb合金相近似的白色色度和肉眼不易察觉的色差(小于1.5)。
採用Gleeble?1500熱模擬實驗機在溫度為600~800°C、應變速率為0.01~10 s?1的熱變形條件下對新型無鎳白色Cu?12Mn?15Zn?1.5Al?0.3Ti?0.14B?0.1Ce(質量分數,%)閤金進行熱壓縮模擬實驗;根據該閤金熱變形行為及熱加工特徵,建立該閤金熱變形的本構方程和熱加工圖。該閤金熱變形過程中變形激活能為203.005 kJ/mol。噹真應變為0.7時,閤金熱加工圖中存在一箇失穩區,此區域的變形溫度為600~700°C,應變速率為0.32~10 s?1。在較適宜的熱變形條件(800°C、10 s?1)下穫得的閤金具有良好的錶麵質量和內部組織。同時,該無鎳閤金具有與傳統鎳白銅Cu?15Ni?24Zn?1.5Pb閤金相近似的白色色度和肉眼不易察覺的色差(小于1.5)。
채용Gleeble?1500열모의실험궤재온도위600~800°C、응변속솔위0.01~10 s?1적열변형조건하대신형무얼백색Cu?12Mn?15Zn?1.5Al?0.3Ti?0.14B?0.1Ce(질량분수,%)합금진행열압축모의실험;근거해합금열변형행위급열가공특정,건립해합금열변형적본구방정화열가공도。해합금열변형과정중변형격활능위203.005 kJ/mol。당진응변위0.7시,합금열가공도중존재일개실은구,차구역적변형온도위600~700°C,응변속솔위0.32~10 s?1。재교괄의적열변형조건(800°C、10 s?1)하획득적합금구유량호적표면질량화내부조직。동시,해무얼합금구유여전통얼백동Cu?15Ni?24Zn?1.5Pb합금상근사적백색색도화육안불역찰각적색차(소우1.5)。
Hot compression test of a novel nickel-free white alloy Cu?12Mn?15Zn?1.5Al?0.3Ti?0.14B?0.1Ce (mass fraction, %) was conducted on a Gleeble?1500 machine in the temperature range of 600?800 °C and the strain rate range of 0.01?10 s?1. The constitutive equation and hot processing map of the alloy were built up according to its hot deformation behavior and hot working characteristics. The deformation activation energy of the alloy is 203.005 kJ/mol. An instability region appears in the hot deformation temperature of 600?700 °C and the strain rate range of 0.32?10 s?1 when the true strain of the alloy is up to 0.7. Under the optimal hot deformation condition of 800 °C and 10 s?1 the prepared specimen has good surface quality and interior structure. The designed nickel-free alloy has very similar white chromaticity with the traditional white copper alloy (Cu?15Ni?24Zn?1.5Pb), and the color difference between them is less than 1.5, which can hardly be distinguished by human eyes.