CAJ | 학술논문

研究赤铁矿法处理高铁闪锌矿浸出液过程中ZnSO 4和MgSO 4浓度对除铁率及赤铁矿渣性质的影响，讨论元素Zn、Mg和S在赤铁矿渣中的存在形态及形成机理。结果表明，除铁率随ZnSO 4浓度的升高而增加，随MgSO 4浓度的升高而降低。增加硫酸盐的浓度可以得到结晶形态更好的晶体。赤铁矿的粒度和S含量随硫酸盐浓度的升高而降低，比表面积随硫酸盐浓度的升高而增加。Zn浓度和Mg浓度的合理存在范围分别为80~100 g/L和小于10 g/L；Zn以ZnSO 4的形式存在于赤铁矿表面，少量的Mg以夹带的方式存在于赤铁矿渣中。
연구적철광법처리고철섬자광침출액과정중ZnSO 4화MgSO 4농도대제철솔급적철광사성질적영향，토론원소Zn、Mg화S재적철광사중적존재형태급형성궤리。결과표명，제철솔수ZnSO 4농도적승고이증가，수MgSO 4농도적승고이강저。증가류산염적농도가이득도결정형태경호적정체。적철광적립도화S함량수류산염농도적승고이강저，비표면적수류산염농도적승고이증가。Zn농도화Mg농도적합리존재범위분별위80~100 g/L화소우10 g/L；Zn이ZnSO 4적형식존재우적철광표면，소량적Mg이협대적방식존재우적철광사중。
The effects of ZnSO 4 and MgSO 4 concentrations on the iron removal rate and the properties of residues for treating the leaching liquor of high iron sphalerite by hematite process were investigated, the existent form and formation mechanism of Zn, Mg and S in hematite were discussed. The results show that the iron removal rate increases with increasing the ZnSO 4 concentration and decreases with increasing the MgSO 4 concentration. Better crystal morphology of precipitates can be obtained by increasing the sulfate concentration. Higher sulfate concentration produced precipitates with finer particle sizes, lower S contents and bigger specific surface area. A reasonable existence range of Zn and Mg are 80~100 g/L and <10 g/L, respectively. Zn exists in hematite surface as ZnSO 4 , low levels of Mg in the precipitates present as tiny liquid inclusions in the hematite particles.