CAJ | 학술논문

采用XRD、XPS和MLA等检测研究海相火山岩型黄铜矿及斑岩型黄铜矿化学浸出的差异性。结果表明：在化学浸出过程中，海相火山岩型黄铜矿与斑岩型黄铜矿浸出特性有很大的差异，这是由于两种黄铜矿表面形成中间产物的性质不同。两种黄铜矿化学浸出的产物除单质硫S 8之外，还有非化学计量的中间产物Cu 3.5 Fe 4 S 2.5、Cu 5 Fe 4 S及Cu 3.5 Fe 1.5 S 5生成。海相火山岩型黄铜矿的中间产物以Cu 3.5 Fe 4 S 2.5为主，斑岩型黄铜矿的中间产物以Cu 3.5 Fe 1.5 S 5为主。海相火山岩型黄铜矿与斑岩型黄铜矿具有不同的溶解途径：海相火山岩型黄铜矿受到H+的腐蚀后矿物中的Cu—S断裂，Cu2+与Fe2+同时溶解，而斑岩型黄铜矿受到H+腐蚀后Fe2+优先溶解。
채용XRD、XPS화MLA등검측연구해상화산암형황동광급반암형황동광화학침출적차이성。결과표명：재화학침출과정중，해상화산암형황동광여반암형황동광침출특성유흔대적차이，저시유우량충황동광표면형성중간산물적성질불동。량충황동광화학침출적산물제단질류S 8지외，환유비화학계량적중간산물Cu 3.5 Fe 4 S 2.5、Cu 5 Fe 4 S급Cu 3.5 Fe 1.5 S 5생성。해상화산암형황동광적중간산물이Cu 3.5 Fe 4 S 2.5위주，반암형황동광적중간산물이Cu 3.5 Fe 1.5 S 5위주。해상화산암형황동광여반암형황동광구유불동적용해도경：해상화산암형황동광수도H+적부식후광물중적Cu—S단렬，Cu2+여Fe2+동시용해，이반암형황동광수도H+부식후Fe2+우선용해。
The chemical leaching different characteristics of chalcopyrite with different genetic types (marine volcanic and porphyry) were investigated by XRD, XPS and MLA analysis. The results show that the difference between marine volcanic chalcopyrite and porphyry chalcopyrite during chemical leaching is generated by intermediate formed on the surface of chalcopyrite with different chemical and structural properties. Nonstoichiometric intermediate products, such as Cu3.5Fe4S2.5, Cu5Fe4S and Cu3.5Fe1.5S5, also form during two kinds of chalcopyrite leaching, besides sulphur S8. The main intermediate product of marine volcanic chalcopyrite is Cu 3.5 Fe 4 S 2.5 , while Cu 3.5 Fe 1.5 S 5 is mainly in porphyry chalcopyrite. The leaching mechanism of marine volcanic chalcopyrite and porphyry chalcopyrite is different. During the leaching process of marine volcanic chalcopyrite, Cu2+and Fe2+are dissolved simultaneously after the broken of Cu—S bond attacked by proton. However, Fe2+dissolves preferentially after the porphyry chalcopyrite is corroded by H+.