中国有色金属学报
中國有色金屬學報
중국유색금속학보
THE CHINESE JOURNAL OF NONFERROUS METALS
2014年
11期
2755-2761
,共7页
张建宇%曾祥勇%韩艳秋%姚金金%吴春京
張建宇%曾祥勇%韓豔鞦%姚金金%吳春京
장건우%증상용%한염추%요금금%오춘경
铜包铝复合材料%充芯连铸%界面%形成机理
銅包鋁複閤材料%充芯連鑄%界麵%形成機理
동포려복합재료%충심련주%계면%형성궤리
copper cladding aluminum composites%core-filling continuous casting%interface%formation mechanism
采用垂直充芯连铸法制备断面尺寸为60 mm×14 mm×7 mm(长×宽×圆角半径)、铜包覆层厚度为2 mm的铜包铝复合材料,并采用扫描电子显微镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)和透射电子显微镜(TEM)等对界面的形貌和组成进行表征。结果表明:铜包铝复合材料界面层在近铜侧主要由平面状的Cu 9 Al 4(I区)和胞状的CuAl 2(II区)两区组成,在近铝侧为α(Al)+CuAl 2伪共晶组织(III区),而在Cu 9 Al 4和CuAl 2之间还残存未转变的高温相Cu 3 Al 2+x。基于分析结果,提出了充芯连铸铜包铝的界面形成机理。
採用垂直充芯連鑄法製備斷麵呎吋為60 mm×14 mm×7 mm(長×寬×圓角半徑)、銅包覆層厚度為2 mm的銅包鋁複閤材料,併採用掃描電子顯微鏡(SEM)、能譜儀(EDS)、X射線衍射儀(XRD)和透射電子顯微鏡(TEM)等對界麵的形貌和組成進行錶徵。結果錶明:銅包鋁複閤材料界麵層在近銅側主要由平麵狀的Cu 9 Al 4(I區)和胞狀的CuAl 2(II區)兩區組成,在近鋁側為α(Al)+CuAl 2偽共晶組織(III區),而在Cu 9 Al 4和CuAl 2之間還殘存未轉變的高溫相Cu 3 Al 2+x。基于分析結果,提齣瞭充芯連鑄銅包鋁的界麵形成機理。
채용수직충심련주법제비단면척촌위60 mm×14 mm×7 mm(장×관×원각반경)、동포복층후도위2 mm적동포려복합재료,병채용소묘전자현미경(SEM)、능보의(EDS)、X사선연사의(XRD)화투사전자현미경(TEM)등대계면적형모화조성진행표정。결과표명:동포려복합재료계면층재근동측주요유평면상적Cu 9 Al 4(I구)화포상적CuAl 2(II구)량구조성,재근려측위α(Al)+CuAl 2위공정조직(III구),이재Cu 9 Al 4화CuAl 2지간환잔존미전변적고온상Cu 3 Al 2+x。기우분석결과,제출료충심련주동포려적계면형성궤리。
Copper cladding aluminum (CCA) composites with the section dimensions of 60 mm×14 mm×7 mm (length×width×round angle radius) and the sheath thickness of 2 mm were fabricated by vertical core-filling continuous casting (VCFC) technology, and the micro-morphology and composition at the interface of CCA composites were characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDS), X-ray diffractometry (XRD) and transmission electron microscopy (TEM). The results show that the interface at the side of Cu is composed of the Cu 9 Al 4 planar layer (zone I) and CuAl 2 cellular layer (zone II), and that at the Al side isα(Al)+CuAl 2 pseudo eutectic structure (zone III) , in addition, the high temperature phase Cu 3 Al 2+x is remained between Cu 9 Al 4 and CuAl 2 . Thus, the formation mechanism of interface in CCA composites fabricated by core-filling continuous casting was proposed.