中国有色金属学报
中國有色金屬學報
중국유색금속학보
THE CHINESE JOURNAL OF NONFERROUS METALS
2014年
11期
2743-2748
,共6页
徐光晨%陈翌庆%刘丽华%Alan LUO%马立坤
徐光晨%陳翌慶%劉麗華%Alan LUO%馬立坤
서광신%진익경%류려화%Alan LUO%마립곤
铝合金%氧化膜%镁/铝复合%La%界面组织
鋁閤金%氧化膜%鎂/鋁複閤%La%界麵組織
려합금%양화막%미/려복합%La%계면조직
aluminum alloy%oxide layer%Mg/Al compound%La%interface structure
利用压铸工艺将液态镁和固态铝液?固复合是一种镁/铝异种材料焊接的新工艺。镁/铝异种活性金属液?固连接的难点首先是固态铝合金属表面存在一层氧化膜,阻碍镁/铝异种活性金属之间形成冶金结合,其次是镁/铝液固复合过程中无法避免地形成大量的金属间化合物,这些脆性相极大地破坏了界面的力学性能。对铝合金表面进行氧化膜去除工艺,并在此基础上,利用自制的液固双金属复合装置将液态镁镧中间合金与经过表面处理的固态铝合金进行液固复合。研究镁合金中的稀土La对镁铝液固扩散连接界面组织及性能的影响。结果表明:镁合金中加入稀土La后,镁铝扩散连接界面处的β-Mg 17 Al 12变少、变细,铸态晶粒细化;大部分La与Al结合生成高熔点、高热稳定性的稀土相Al 11 La 3相;当镁合金中含有1%(质量分数)稀土La时,界面可达到最大的抗剪强度88.5MPa。
利用壓鑄工藝將液態鎂和固態鋁液?固複閤是一種鎂/鋁異種材料銲接的新工藝。鎂/鋁異種活性金屬液?固連接的難點首先是固態鋁閤金屬錶麵存在一層氧化膜,阻礙鎂/鋁異種活性金屬之間形成冶金結閤,其次是鎂/鋁液固複閤過程中無法避免地形成大量的金屬間化閤物,這些脆性相極大地破壞瞭界麵的力學性能。對鋁閤金錶麵進行氧化膜去除工藝,併在此基礎上,利用自製的液固雙金屬複閤裝置將液態鎂鑭中間閤金與經過錶麵處理的固態鋁閤金進行液固複閤。研究鎂閤金中的稀土La對鎂鋁液固擴散連接界麵組織及性能的影響。結果錶明:鎂閤金中加入稀土La後,鎂鋁擴散連接界麵處的β-Mg 17 Al 12變少、變細,鑄態晶粒細化;大部分La與Al結閤生成高鎔點、高熱穩定性的稀土相Al 11 La 3相;噹鎂閤金中含有1%(質量分數)稀土La時,界麵可達到最大的抗剪彊度88.5MPa。
이용압주공예장액태미화고태려액?고복합시일충미/려이충재료한접적신공예。미/려이충활성금속액?고련접적난점수선시고태려합금속표면존재일층양화막,조애미/려이충활성금속지간형성야금결합,기차시미/려액고복합과정중무법피면지형성대량적금속간화합물,저사취성상겁대지파배료계면적역학성능。대려합금표면진행양화막거제공예,병재차기출상,이용자제적액고쌍금속복합장치장액태미란중간합금여경과표면처리적고태려합금진행액고복합。연구미합금중적희토La대미려액고확산련접계면조직급성능적영향。결과표명:미합금중가입희토La후,미려확산련접계면처적β-Mg 17 Al 12변소、변세,주태정립세화;대부분La여Al결합생성고용점、고열은정성적희토상Al 11 La 3상;당미합금중함유1%(질량분수)희토La시,계면가체도최대적항전강도88.5MPa。
Die-casting is a new magnesium/aluminum dissimilar welding process via casting liquid Mg alloy onto the solid Al alloy substrate. The difficulty of liquid?solid connection of magnesium/aluminum is the nature oxide layer on the solid Al alloy substrate surface that usually prevents metallurgical bonding between the magnesium and aluminum. During this process, the formation of some intermetallic compounds with a high hardness and brittleness over the interface would deteriorate the mechanical property of materials. The process of removing the oxide layer on solid Al substrate surface was investigated, and on this basis, the melt magnesium alloy was cast onto the solid aluminum alloy A390 by using home-made liquid-solid bimetal composite device. The effect of La on the structures and properties of the liquid-solid diffusion bonding interface of Mg/Al was researched. The results indicate that after adding the rare earth La into the magnesium alloys, β-Mg 17 Al 12 at the interface of magnesium aluminum diffusion bonding gradually becomes less and thinner, and the cast grain is gradually refined. Most of La and Al combine to generate high melting point and high heat stability of rare earth phase-Al 11 La 3 phase. When the magnesium alloys contain 1%rare earth La, the maximal shearing strength of the interface can achieve 88.5 MPa.