化学通报（网络版）
化學通報（網絡版）
화학통보（망락판）
Chemistry Online
2012年
1期
1-7
,共7页
游倩倩%张普玉*%张怀敏
遊倩倩%張普玉*%張懷敏
유천천%장보옥*%장부민
离子液体%自由基聚合%共聚物
離子液體%自由基聚閤%共聚物
리자액체%자유기취합%공취물
Ionic liquid%Radical polymerization%Copolymer
离子液体具有独特的理化性能，作为一种环境友好、“可设计性”的溶剂，近年来成为化学领域的热点和前沿。离子液体作为自由基聚合反应的溶剂，对聚合速率、聚合产物结构及性能都有一定的影响。离子液体已经被较为广泛地应用于不同介质、不同物相中的自由基聚合反应，但是并不完全。近两年来已有研究工作者将离子液体应用于微乳液和气相中的自由基聚合反应，并和其他有机溶剂及水溶液共同调控自由基聚合反应。离子液体也首次应用于有机碲调控的自由基聚合反应和氮氧稳定的自由基聚合反应。同时离子液体也可以调控自由基聚合反应后聚合物的结构和形貌，是一种很好的进行聚合物自组装的溶剂。本文主要综述了近年来离子液体对自由基聚合反应的影响，特别是对聚合产物结构及性能的影响，最后展望了离子液体在聚合反应中的应用前景。
離子液體具有獨特的理化性能，作為一種環境友好、“可設計性”的溶劑，近年來成為化學領域的熱點和前沿。離子液體作為自由基聚閤反應的溶劑，對聚閤速率、聚閤產物結構及性能都有一定的影響。離子液體已經被較為廣汎地應用于不同介質、不同物相中的自由基聚閤反應，但是併不完全。近兩年來已有研究工作者將離子液體應用于微乳液和氣相中的自由基聚閤反應，併和其他有機溶劑及水溶液共同調控自由基聚閤反應。離子液體也首次應用于有機碲調控的自由基聚閤反應和氮氧穩定的自由基聚閤反應。同時離子液體也可以調控自由基聚閤反應後聚閤物的結構和形貌，是一種很好的進行聚閤物自組裝的溶劑。本文主要綜述瞭近年來離子液體對自由基聚閤反應的影響，特彆是對聚閤產物結構及性能的影響，最後展望瞭離子液體在聚閤反應中的應用前景。
리자액체구유독특적이화성능，작위일충배경우호、“가설계성”적용제，근년래성위화학영역적열점화전연。리자액체작위자유기취합반응적용제，대취합속솔、취합산물결구급성능도유일정적영향。리자액체이경피교위엄범지응용우불동개질、불동물상중적자유기취합반응，단시병불완전。근량년래이유연구공작자장리자액체응용우미유액화기상중적자유기취합반응，병화기타유궤용제급수용액공동조공자유기취합반응。리자액체야수차응용우유궤제조공적자유기취합반응화담양은정적자유기취합반응。동시리자액체야가이조공자유기취합반응후취합물적결구화형모，시일충흔호적진행취합물자조장적용제。본문주요종술료근년래리자액체대자유기취합반응적영향，특별시대취합산물결구급성능적영향，최후전망료리자액체재취합반응중적응용전경。
With many unique physical and chemical characteristics, ionic liquids are the novel green and“designable” solvents, and they have become the frontier of chemistry research in recent years. Ionic liquids have an effect on the polymerization rate, the structure and properties of polymerization products as the solvents of radical polymerization. Ionic liquids have been somewhat widely used in the different media, different physical phases of radical polymerization. But there are other media and physical phases, in which ionic liquids have not been used. In the past two years, some researchers have firstly used ionic liquids in the microemulsion radical polymerization and gas phase radical polymerization, and then to control the radical polymerization with other organic solvents and aqueous solutions in common. Ionic liquids have also been used in the Organotellurium-Mediated living radical polymerization (TERP) and Nitroxide-Mediated controlled/living radical copolymerization (NMP) firstly. Meanwhile, ionic liquids can also control the structure and morphology of the polymers obtained by the radical polymerization, which implied that ionic liquids were good solvents in the polymer self-assembly. This paper summarized the influence of the ionic liquids on the radical polymerization and the structure and properties of its polymers. Furthermore, the future development trends of ionic liquids in the application of the radical polymerization were also discussed.
