CAJ | 학술논문

目的评价十二烷基聚氧乙烯聚氧丙烯醚(LSmn)系列表面活性剂与不同类型表面活性剂复配的协同效应.方法测定LS36、LS45、LS54分别与离子型表面活性剂十六烷基三甲基溴化铵(CTAB)、十二烷基磺酸钠(AS)、双-2-乙基己基琥珀酸磺酸钠(AOT)及全氟辛酸钠(OBS)复配的表面张力~浓度对数关系(γ~log c)曲线,计算它们在溶液表面吸附层及胶束中的组成、分子相互作用参数及分子交换能.通过交换能,判断产生的协同效应效果.结果与结论所有混合体系的分子交换能均为负值,与纯组分的表面活性比较,复配后不论是形成胶束的能力,还是降低表面张力的效率和能力均出现显著的协同效应.
목적평개십이완기취양을희취양병희미(LSmn)계렬표면활성제여불동류형표면활성제복배적협동효응.방법측정LS36、LS45、LS54분별여리자형표면활성제십륙완기삼갑기추화안(CTAB)、십이완기광산납(AS)、쌍-2-을기기기호박산광산납(AOT)급전불신산납(OBS)복배적표면장력~농도대수관계(γ~log c)곡선,계산타문재용액표면흡부층급효속중적조성、분자상호작용삼수급분자교환능.통과교환능,판단산생적협동효응효과.결과여결론소유혼합체계적분자교환능균위부치,여순조분적표면활성비교,복배후불론시형성효속적능력,환시강저표면장력적효솔화능력균출현현저적협동효응.
@@@@Objective To evaluate the synergisms of systems between LSmn surfactants and other types of surfactants. Methods Curves of surface tension vs. the total concentration of the binary system of nonionic surfactants-linear dodecyl polyoxyethylene polyoxypropylene ether C12H25(EO)m(PO)nH, which is also written as LSmn, with different structural ionic surfactants have been measured at 25℃. The series of LSmn are LS36, LS45 and LS54, and the ionic surfactants are cetyltrimethylammonium bromide (CTAB), sodium dodecylesulfonate (AS), sodium of double-2-ethyl hexyl ethylene dicarboxylic acid sulfonic acid (AOT) and sodium perfluorocarylate (OBS). The composition, the parameters of molecule interaction and the molecule-exchanging energies both in the surface phase and in the micelle phase have been obtained from the curves. Results The molecule-exchanging energies are negative. Conclusion All the synergisms in mixed micelle formation and in surface tension reduction efficiency as well as effectiveness remarkably appear in all the studied mixtures.