食品与药品
食品與藥品
식품여약품
FOOD AND DRUG
2013年
2期
110-111
,共2页
况成裕%姜立会%丁双婷%刘胜来
況成裕%薑立會%丁雙婷%劉勝來
황성유%강립회%정쌍정%류성래
见血飞%虎耳草素%飞龙掌血内酯%异虎耳草素
見血飛%虎耳草素%飛龍掌血內酯%異虎耳草素
견혈비%호이초소%비룡장혈내지%이호이초소
Caesalpinia cucullata Roxb.%pimpinellin%toddalolactone%isopimplnellin
目的研究见血飞的化学成分.方法利用色谱硅胶、Sephadex LH20与RP-18柱分离,NMR法等鉴定结构.结果分离出7个化合物,分别鉴定为:虎耳草素(pimpinellin,Fec-Ⅰ)、飞龙掌血内酯(toddalolactone,Fec-Ⅱ)、异虎耳草素(isopimplnellin,Fec-Ⅲ)、茵芋碱(skimmianine,Fec-Ⅳ)、3-乙酰基-α-香树脂醇(3-acetyl-α-amyranol,Fec-Ⅴ)、β-谷甾醇(β-sitosterol,Fec-Ⅵ)、7-甲氧基-5,4'-二羟基二氢黄酮醇(7-methoxy-5,4'- dihydroxyflavanonol,Fec-Ⅶ).结论其中化合物Ⅶ为首次从芸香科植物中分离得到.
目的研究見血飛的化學成分.方法利用色譜硅膠、Sephadex LH20與RP-18柱分離,NMR法等鑒定結構.結果分離齣7箇化閤物,分彆鑒定為:虎耳草素(pimpinellin,Fec-Ⅰ)、飛龍掌血內酯(toddalolactone,Fec-Ⅱ)、異虎耳草素(isopimplnellin,Fec-Ⅲ)、茵芋堿(skimmianine,Fec-Ⅳ)、3-乙酰基-α-香樹脂醇(3-acetyl-α-amyranol,Fec-Ⅴ)、β-穀甾醇(β-sitosterol,Fec-Ⅵ)、7-甲氧基-5,4'-二羥基二氫黃酮醇(7-methoxy-5,4'- dihydroxyflavanonol,Fec-Ⅶ).結論其中化閤物Ⅶ為首次從蕓香科植物中分離得到.
목적연구견혈비적화학성분.방법이용색보규효、Sephadex LH20여RP-18주분리,NMR법등감정결구.결과분리출7개화합물,분별감정위:호이초소(pimpinellin,Fec-Ⅰ)、비룡장혈내지(toddalolactone,Fec-Ⅱ)、이호이초소(isopimplnellin,Fec-Ⅲ)、인우감(skimmianine,Fec-Ⅳ)、3-을선기-α-향수지순(3-acetyl-α-amyranol,Fec-Ⅴ)、β-곡치순(β-sitosterol,Fec-Ⅵ)、7-갑양기-5,4'-이간기이경황동순(7-methoxy-5,4'- dihydroxyflavanonol,Fec-Ⅶ).결론기중화합물Ⅶ위수차종예향과식물중분리득도.
@@@@Objective To study the chemical constituents of Caesalpinia cucullata Roxb.. Methods The chemical constituents were separated by silica gel, Sephadex LH20 and RP-18 column chromatography, and their structures were identified by 1H-NMR and 13C-NMR. Results Seven compounds were isolated and identified as: pimpinellin (Fec-Ⅰ), toddalolactone (Fec-Ⅱ), isopimplnellin (Fec-Ⅲ), skimmianine (Fec-Ⅳ), 3-acetyl -α-amyranol (Fec-Ⅴ),β-sitosterol (Fec-Ⅵ) and 7-methoxy-5, 4 'dihydroxyflavanonol (Fec-Ⅶ). Conclusion Compounds Ⅶ is isolated from Rutaceae for the first time.
