化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2013年
5期
1025-1029
,共5页
周圆%汤旭东%叶方伟%曾德平%王华
週圓%湯旭東%葉方偉%曾德平%王華
주원%탕욱동%협방위%증덕평%왕화
高强度聚焦超声%柴油%乳化%高效%稳定性
高彊度聚焦超聲%柴油%乳化%高效%穩定性
고강도취초초성%시유%유화%고효%은정성
high intensity focused ultrasound%diesel%emulsification%efficient%stability
采用高强度聚焦超声新技术对柴油乳化进行了研究.实验选择Span80和Tween80两种乳化剂按不同比例进行复配,乳化剂用量(质量分数)为0.9%,含水率为9%.实验结果表明,球形超声聚焦设备不但可以为乳化提供较高能量,而且可以产生强烈的空化和搅拌.高速摄影显示,空化效应和界面不稳定性是这种球形高强度聚焦超声产生乳化的机制.实验结果显示,最佳HLB值为5.4,最佳输入电功率为950 W,乳化300 s就可以得到比较稳定的柴油乳液.乳液粒径可以达到0.5μm,且分布均匀,稳定时间在6个月以上.通过对比,高强度聚焦超声的乳化效果和乳化效率明显优于变幅杆式超声发生器和磁力搅拌器,为柴油乳化提供了一个具有重要意义的乳化方式.
採用高彊度聚焦超聲新技術對柴油乳化進行瞭研究.實驗選擇Span80和Tween80兩種乳化劑按不同比例進行複配,乳化劑用量(質量分數)為0.9%,含水率為9%.實驗結果錶明,毬形超聲聚焦設備不但可以為乳化提供較高能量,而且可以產生彊烈的空化和攪拌.高速攝影顯示,空化效應和界麵不穩定性是這種毬形高彊度聚焦超聲產生乳化的機製.實驗結果顯示,最佳HLB值為5.4,最佳輸入電功率為950 W,乳化300 s就可以得到比較穩定的柴油乳液.乳液粒徑可以達到0.5μm,且分佈均勻,穩定時間在6箇月以上.通過對比,高彊度聚焦超聲的乳化效果和乳化效率明顯優于變幅桿式超聲髮生器和磁力攪拌器,為柴油乳化提供瞭一箇具有重要意義的乳化方式.
채용고강도취초초성신기술대시유유화진행료연구.실험선택Span80화Tween80량충유화제안불동비례진행복배,유화제용량(질량분수)위0.9%,함수솔위9%.실험결과표명,구형초성취초설비불단가이위유화제공교고능량,이차가이산생강렬적공화화교반.고속섭영현시,공화효응화계면불은정성시저충구형고강도취초초성산생유화적궤제.실험결과현시,최가HLB치위5.4,최가수입전공솔위950 W,유화300 s취가이득도비교은정적시유유액.유액립경가이체도0.5μm,차분포균균,은정시간재6개월이상.통과대비,고강도취초초성적유화효과화유화효솔명현우우변폭간식초성발생기화자력교반기,위시유유화제공료일개구유중요의의적유화방식.
A new technology of high intensity focused ultrasound was used to study the emulsion of water-in-diesel. The surfactants Span80 and Tween80 were chosen. The mass fraction of surfactant and water were 0.9%and 9%respectively. The result showed that spherical focused ultrasound setup could not only provide high energy,but also induce intensive cavitation and stir. The using of high speed photography technology showed that cavitation and interfacial instability also were the main principle of this kind of emulsification. The optimum HLB was 5.4 and the optimum input power was 950W. Insonation time 300s could produce fine emulsions. With optimum HLB value 5.4,water could be well-distributed in diesel and the droplet size was as low as 0.5μm. The stabilization time of the emulsion could be more than six months. Compared with using insonation equipment with sonotrode and magnetic stirrer methods,the spherical focused ultrasound setup was better both in effect and efficiency. This setup provided a novel and significant method for water-in-diesel emulsification.