中国有色金属学报
中國有色金屬學報
중국유색금속학보
THE CHINESE JOURNAL OF NONFERROUS METALS
2013年
3期
635-644
,共10页
冯凯%黄晓锋%马颖%阎峰云%郝远
馮凱%黃曉鋒%馬穎%閻峰雲%郝遠
풍개%황효봉%마영%염봉운%학원
ZA74镁合金%部分重熔%半固态%非枝晶组织%演变机理
ZA74鎂閤金%部分重鎔%半固態%非枝晶組織%縯變機理
ZA74미합금%부분중용%반고태%비지정조직%연변궤리
ZA74 magnesium alloy%partial remelting%semi-solid%non-dendritic microstructure%evolution mechanism
采用等温热处理法对ZA74镁合金在部分重熔过程中非枝晶组织的演变过程和机理进行研究.结果表明:在重熔过程中,ZA74合金原始组织中沿着晶界分布的Mg32(Al,Zn)49共晶相逐渐向α-Mg基体扩散溶解,当温度达到共晶熔化后,剩余部分开始熔化.非枝晶组织的演变是在体系自由能降低的驱动下完成的,主要机制是共晶组织的固溶,溶质原子扩散,枝晶组织的粗化、分离、球化以及晶粒的合并和长大.其中,ZA74合金固相颗粒的分离是由溶质扩散、能量起伏、成分起伏等因素造成液相沿亚晶界浸渗和根部重熔两种机制起主导作用.
採用等溫熱處理法對ZA74鎂閤金在部分重鎔過程中非枝晶組織的縯變過程和機理進行研究.結果錶明:在重鎔過程中,ZA74閤金原始組織中沿著晶界分佈的Mg32(Al,Zn)49共晶相逐漸嚮α-Mg基體擴散溶解,噹溫度達到共晶鎔化後,剩餘部分開始鎔化.非枝晶組織的縯變是在體繫自由能降低的驅動下完成的,主要機製是共晶組織的固溶,溶質原子擴散,枝晶組織的粗化、分離、毬化以及晶粒的閤併和長大.其中,ZA74閤金固相顆粒的分離是由溶質擴散、能量起伏、成分起伏等因素造成液相沿亞晶界浸滲和根部重鎔兩種機製起主導作用.
채용등온열처리법대ZA74미합금재부분중용과정중비지정조직적연변과정화궤리진행연구.결과표명:재중용과정중,ZA74합금원시조직중연착정계분포적Mg32(Al,Zn)49공정상축점향α-Mg기체확산용해,당온도체도공정용화후,잉여부분개시용화.비지정조직적연변시재체계자유능강저적구동하완성적,주요궤제시공정조직적고용,용질원자확산,지정조직적조화、분리、구화이급정립적합병화장대.기중,ZA74합금고상과립적분리시유용질확산、능량기복、성분기복등인소조성액상연아정계침삼화근부중용량충궤제기주도작용.
@@@@The non-dendritic microstructure evolution process and mechanism analysis of ZA74 magnesium alloy during partial remelting were investigated by isothermal heat-treatment. The results indicate that the Mg32(Al,Zn)49 eutectic phases distribute on grain boundary of ZA74 alloy initial microstructure, which gradually dissolves intoα-Mg matrix due to the diffusion of the solute and the remainder is melted when the temperature reaches up to eutectic melted. The evolution of non-dendritic microstructure is driven by the free energy reduction. The main mechanisms are the eutectic microstructure solution, solute diffusion, coarsening, dendrite separation, spheroidization and final coarsening during partial remelting. Furthermore, the appearance of subboundary and root remelting results from the solute diffusion, energy fluctuation and constituent fluctuation which are the separation mechanisms of ZA74 particle during partial remelting.