化学通报（网络版）
化學通報（網絡版）
화학통보（망락판）
Chemistry Online
2001年
1期
,共1页
雷惊雷%张存中%杨迈之%蔡生民**
雷驚雷%張存中%楊邁之%蔡生民**
뢰량뢰%장존중%양매지%채생민**
金属光电子注入法%光电化学%溶剂化电子%饱和全氟烷烃
金屬光電子註入法%光電化學%溶劑化電子%飽和全氟烷烴
금속광전자주입법%광전화학%용제화전자%포화전불완경
Photoelectron injection%Photoelectrochemistry%Solvated electron%Perfluoro compounds
金属光电子注入法是近二三十年内才发展起来的一种新型光电化学方法,通常被用于某些基础理论研究.在介绍了金属光电子注入法的基本原理、实验装置的基础上,概述了这种方法在电化学理论研究中的应用以及将其用于还原饱和全氟烷烃的探索性工作,并对这种方法的优缺点进行了评述.
金屬光電子註入法是近二三十年內纔髮展起來的一種新型光電化學方法,通常被用于某些基礎理論研究.在介紹瞭金屬光電子註入法的基本原理、實驗裝置的基礎上,概述瞭這種方法在電化學理論研究中的應用以及將其用于還原飽和全氟烷烴的探索性工作,併對這種方法的優缺點進行瞭評述.
금속광전자주입법시근이삼십년내재발전기래적일충신형광전화학방법,통상피용우모사기출이론연구.재개소료금속광전자주입법적기본원리、실험장치적기출상,개술료저충방법재전화학이론연구중적응용이급장기용우환원포화전불완경적탐색성공작,병대저충방법적우결점진행료평술.
Photoelectron injection from metal into electrolyte solutions is a new photoelectrochemical method developed in the past decades of years, which is usually used for theoretical study of the metal/solution interface phenomena, the movement of electrons in solutions, and so on. In this paper, both the theoretical and experimental parts of this method are first introduced. The application of photoelectron injection from metal into electrolyte solutions in the field of theoretical electrochemical studies is reviewed. The exploration by using this technique to reduce some inert compounds such as perfluoro compounds, which could not be reduced by ordinary chemical approaches, is also described.
