化学通报（网络版）
化學通報（網絡版）
화학통보（망락판）
Chemistry Online
2002年
1期
,共1页
曹玲华%解正峰%周传健%刘育亭
曹玲華%解正峰%週傳健%劉育亭
조령화%해정봉%주전건%류육정
糖基异硫氰酸酯%硫代磷酰二肼%硫代磷酸芳基酯%合成
糖基異硫氰痠酯%硫代燐酰二肼%硫代燐痠芳基酯%閤成
당기이류청산지%류대린선이정%류대린산방기지%합성
Glycosyl isothiocyanates%Thiophosphoric dihydrazide%Thiophosphoric aryl ester%Synthesis
芳氧基亚磷酰二氯(1A,1B)与PSCl3作用,得到芳氧基硫代亚磷酰二氯(2A,2B),肼解后得到芳氧基硫代磷酰二肼(3A,3B),将它们分别与糖基异硫氰酸酯(4a~4e)在苯中回流,生成相应的双(N-糖基-硫代氨基脲-2-基)硫代磷酸芳基酯(5a~5d,6a~6c,6e),它们的结构经IR,1H NMR,31P NMR, MS和元素分析加以确证.
芳氧基亞燐酰二氯(1A,1B)與PSCl3作用,得到芳氧基硫代亞燐酰二氯(2A,2B),肼解後得到芳氧基硫代燐酰二肼(3A,3B),將它們分彆與糖基異硫氰痠酯(4a~4e)在苯中迴流,生成相應的雙(N-糖基-硫代氨基脲-2-基)硫代燐痠芳基酯(5a~5d,6a~6c,6e),它們的結構經IR,1H NMR,31P NMR, MS和元素分析加以確證.
방양기아린선이록(1A,1B)여PSCl3작용,득도방양기류대아린선이록(2A,2B),정해후득도방양기류대린선이정(3A,3B),장타문분별여당기이류청산지(4a~4e)재분중회류,생성상응적쌍(N-당기-류대안기뇨-2-기)류대린산방기지(5a~5d,6a~6c,6e),타문적결구경IR,1H NMR,31P NMR, MS화원소분석가이학증.
Reactions of aryloxyphosphorous dichloride (1A,1B) with PSCl3 gave corresponding aryloxythiophosphoric dichloride (2A,2B), then hydrazinolyzation gave aryloxythiophosphoric dihydrazide (3A,3B). Reactions of 3a and 3b with glycosyl isothiocyanates (4a~4e) in benzene, gave corresponding bis(N-glycosyl-hydrazinecarbothioamide-2-yl)thiophosphoric esters(5a~5d,6a~6c,6e). Their structures were confirmed by IR, 1H NMR, 31P NMR, MS and elemental analysis.
