化学通报（网络版）
化學通報（網絡版）
화학통보（망락판）
Chemistry Online
2004年
1期
,共1页
耿后安%魏锡文*%李兵%杨丽君%张朝阳
耿後安%魏錫文*%李兵%楊麗君%張朝暘
경후안%위석문*%리병%양려군%장조양
化学镀%次亚磷酸根%活化%解离%从头计算
化學鍍%次亞燐痠根%活化%解離%從頭計算
화학도%차아린산근%활화%해리%종두계산
Electroless plating%H2PO2-%Activation%Dissociation%AB initio
应用量子化学计算和红外光谱等实验,讨论了H2PO2-的结构特征和电子分布,研究了在惰性基体上镍活化化学镀镍时,镀液体系中H2PO2-的解离途径,对其中P-H键的均裂和异裂方式进行了深入的考察,并分析了溶剂效应和活性物质对H2PO2-解离的影响.
應用量子化學計算和紅外光譜等實驗,討論瞭H2PO2-的結構特徵和電子分佈,研究瞭在惰性基體上鎳活化化學鍍鎳時,鍍液體繫中H2PO2-的解離途徑,對其中P-H鍵的均裂和異裂方式進行瞭深入的攷察,併分析瞭溶劑效應和活性物質對H2PO2-解離的影響.
응용양자화학계산화홍외광보등실험,토론료H2PO2-적결구특정화전자분포,연구료재타성기체상얼활화화학도얼시,도액체계중H2PO2-적해리도경,대기중P-H건적균렬화이렬방식진행료심입적고찰,병분석료용제효응화활성물질대H2PO2-해리적영향.
In this paper, the structural characteristics and electro-structure of H2PO2- were discussed by means of FTIR and ab initio. The dissociating route of H2PO2-, which is in the process of electroless nickel plating activated by nickel on inertia groups, has been investigated. The average crack and different crack of P-H bond were deliberately analyzed. Moreover, the influence of both solvent and active matter on H2PO2- dissociation was studied.
