化学通报(网络版)
化學通報(網絡版)
화학통보(망락판)
Chemistry Online
2004年
1期
,共1页
赵公大%吕迎%奚祖威%高爽*
趙公大%呂迎%奚祖威%高爽*
조공대%려영%해조위%고상*
催化氧化%醇%H2O2
催化氧化%醇%H2O2
최화양화%순%H2O2
Catalytic oxidation%Alcohols%H2O2
综述了以H2O2作为氧化剂的醇类催化氧化的研究进展.归纳了H2O2-金属催化剂体系的氧化机制,从多相催化与匀相催化两方面讨论了在精细有机合成中有广泛应用的绿色氧化方法.指出了醇类的H2O2催化氧化体系的工业发展方向.
綜述瞭以H2O2作為氧化劑的醇類催化氧化的研究進展.歸納瞭H2O2-金屬催化劑體繫的氧化機製,從多相催化與勻相催化兩方麵討論瞭在精細有機閤成中有廣汎應用的綠色氧化方法.指齣瞭醇類的H2O2催化氧化體繫的工業髮展方嚮.
종술료이H2O2작위양화제적순류최화양화적연구진전.귀납료H2O2-금속최화제체계적양화궤제,종다상최화여균상최화량방면토론료재정세유궤합성중유엄범응용적록색양화방법.지출료순류적H2O2최화양화체계적공업발전방향.
The recent advances in selective oxidation of alcohols with aqueous hydrogen peroxide were reviewed. The oxidation mechanism for H2O2-metal-catalyst was induced. The green oxidation methods in fine chemistry were discussed in both heterogeneous catalysis and homogeneous catalysis. The direction in industry development of oxidation of alcohols with aqueous hydrogen peroxide was described.