CAJ | 학술논문

将固体超强酸S2O82-/TiO2用于催化β-蒎烯的异构化反应,结果表明,该催化剂具有很高的催化活性和较好的选择性.异构化反应的主产物为莰烯,副产物主要是苧烯、蒈烯、三环烯等.异构化反应的最佳条件为,反应温度80℃,反应时间4h,催化剂用量为β-蒎烯质量的3%.在此条件下,β-蒎烯转化率为99.96%,莰烯选择性55.63%.
장고체초강산S2O82-/TiO2용우최화β-파희적이구화반응,결과표명,해최화제구유흔고적최화활성화교호적선택성.이구화반응적주산물위감희,부산물주요시저희、개희、삼배희등.이구화반응적최가조건위,반응온도80℃,반응시간4h,최화제용량위β-파희질량적3%.재차조건하,β-파희전화솔위99.96%,감희선택성55.63%.
The isomerization reaction of β-pinene catalyzed by solid superacid S2O82-/TiO2 was performed. The results showed that the catalyst had strong catalytic activity and better selectivity. The main product of isomerization reaction was camphene and its by-products were limonene, carene and tricyclene etc. The factors influencing the isomerization reaction were investigated . The optimal reaction conditions were as follows:the reaction temperature 80℃, the reaction time 4h and the use level of catalyst S2O82-/TiO2 3% of the mass of β-pinene. Under the above-mentioned optimal reaction conditions, the conversion ofβ-pinene could reach 99.96%and the selectivity of camphene could reach 55.63%.