化学通报（网络版）
化學通報（網絡版）
화학통보（망락판）
Chemistry Online
2005年
1期
1-6
,共6页
水分子簇%氢键%似共价键
水分子簇%氫鍵%似共價鍵
수분자족%경건%사공개건
Water clusters%Hydrogen bond%Quasi-covalent bond
概述了近年来为揭示水分子簇存在形态的成因所做的理论和实验研究,指出除范德华力外,氢键和似共价键是水分子间的主要作用力.总结了水分子簇中氢键的四种作用方式,包括协同效应、氢键的转动、氢键的振动以及氢键变换;分别讨论了这四种作用方式以及似共价键对水分子簇存在状态的影响,最后对该领域的研究前景作了展望.
概述瞭近年來為揭示水分子簇存在形態的成因所做的理論和實驗研究,指齣除範德華力外,氫鍵和似共價鍵是水分子間的主要作用力.總結瞭水分子簇中氫鍵的四種作用方式,包括協同效應、氫鍵的轉動、氫鍵的振動以及氫鍵變換;分彆討論瞭這四種作用方式以及似共價鍵對水分子簇存在狀態的影響,最後對該領域的研究前景作瞭展望.
개술료근년래위게시수분자족존재형태적성인소주적이론화실험연구,지출제범덕화력외,경건화사공개건시수분자간적주요작용력.총결료수분자족중경건적사충작용방식,포괄협동효응、경건적전동、경건적진동이급경건변환;분별토론료저사충작용방식이급사공개건대수분자족존재상태적영향,최후대해영역적연구전경작료전망.
Theoretical and experimental studies that reveal the formation of water clusters have been summarized. Besides van der Waals force, hydrogen bonds and quasi-covalent bonds between water molecules are major forces. Four kinds of kinetic motions of hydrogen bonds in water clusters are outlined, including cooperative effect, rotation, vibration and inter conversion, and the effects on the structure of water clusters caused by quasi-covalent bonds and H-bond kinetic motions are explained in detail. Finally, the perspective in this research field is also discussed.
