化学通报（网络版）
化學通報（網絡版）
화학통보（망락판）
Chemistry Online
2008年
1期
1-5
,共5页
导电高分子%聚吲哚及其衍生物%电化学聚合%三氟化硼乙醚%荧光特性
導電高分子%聚吲哚及其衍生物%電化學聚閤%三氟化硼乙醚%熒光特性
도전고분자%취신타급기연생물%전화학취합%삼불화붕을미%형광특성
Conducting polymers%Polyindole derivatives%Electrochemical polymerization%Boron trifluoride diethyl etherate%Fluorescence properties
在三氟化硼乙醚及其混合电解质中,吲哚及其衍生物阳极氧化可以获得高质量的聚吲哚及其衍生物膜:聚吲哚、聚(5-甲基吲哚)、聚(5-硝基吲哚)、聚(5-氰基吲哚)、聚(5-溴吲哚).它们可溶于DMSO和THF中.聚吲哚及其衍生物具有良好的荧光性质;单体的发射光谱与取代基有关,而聚合物的发射光谱几乎不受取代基的影响.电子离域程度增大,使得聚合物的激发和发射光谱红移,宽的分子量分布则会使聚合物的激发和发射光谱变宽.
在三氟化硼乙醚及其混閤電解質中,吲哚及其衍生物暘極氧化可以穫得高質量的聚吲哚及其衍生物膜:聚吲哚、聚(5-甲基吲哚)、聚(5-硝基吲哚)、聚(5-氰基吲哚)、聚(5-溴吲哚).它們可溶于DMSO和THF中.聚吲哚及其衍生物具有良好的熒光性質;單體的髮射光譜與取代基有關,而聚閤物的髮射光譜幾乎不受取代基的影響.電子離域程度增大,使得聚閤物的激髮和髮射光譜紅移,寬的分子量分佈則會使聚閤物的激髮和髮射光譜變寬.
재삼불화붕을미급기혼합전해질중,신타급기연생물양겁양화가이획득고질량적취신타급기연생물막:취신타、취(5-갑기신타)、취(5-초기신타)、취(5-청기신타)、취(5-추신타).타문가용우DMSO화THF중.취신타급기연생물구유량호적형광성질;단체적발사광보여취대기유관,이취합물적발사광보궤호불수취대기적영향.전자리역정도증대,사득취합물적격발화발사광보홍이,관적분자량분포칙회사취합물적격발화발사광보변관.
High quality polyindoles films, such as polyindole, poly (5-methylindole), poly (5-nitroindole), poly (5-cyanoindole), poly (5-bromoindole), were synthesized electrochemically by direct anodic oxidation of indole and its derivatives in boron trifluoride diethyl etherate (BFEE) or its mixed electrolytes. They were soluble in dimethyl sulfoxide (DMSO) and tetrahydrofuran (THF). The fluorescent emission properties of indole and its derivatives were strongly dependent on the nature of the substituent, but this dependent is almost not observed in the synthesized polymers. The excitation and emission spectra of the polymer species showed a significant red shift compared to the monomers, in consistent with their greater extent of electron delocalisation. The broader excitation and emission spectra of polyindoles can be ascribed to the wide molar distribution of as-prepared polymers.
