化学通报(网络版)
化學通報(網絡版)
화학통보(망락판)
Chemistry Online
2008年
1期
,共1页
含糖聚合物%可控/“活性”聚合%离子聚合%活性自由基聚合%开环聚合
含糖聚閤物%可控/“活性”聚閤%離子聚閤%活性自由基聚閤%開環聚閤
함당취합물%가공/“활성”취합%리자취합%활성자유기취합%개배취합
Glycopolymer%Controlled/living polymerization%Ionic polymerization%Living radical polymerization%Ring-opening polymerization (ROP)
活性聚合技术的进步,使设计合成结构可控的含糖聚合物成为可能.本文介绍了阴离子聚合、阳离子聚合、原子转移自由基聚合、可逆加成断裂链转移聚合、硝基氧介导聚合、开环聚合和开环易位聚合等一系列可控/“活性”聚合技术在合成含糖聚合物中的应用,并对这一领域所取得的研究进展及现状进行了综述.
活性聚閤技術的進步,使設計閤成結構可控的含糖聚閤物成為可能.本文介紹瞭陰離子聚閤、暘離子聚閤、原子轉移自由基聚閤、可逆加成斷裂鏈轉移聚閤、硝基氧介導聚閤、開環聚閤和開環易位聚閤等一繫列可控/“活性”聚閤技術在閤成含糖聚閤物中的應用,併對這一領域所取得的研究進展及現狀進行瞭綜述.
활성취합기술적진보,사설계합성결구가공적함당취합물성위가능.본문개소료음리자취합、양리자취합、원자전이자유기취합、가역가성단렬련전이취합、초기양개도취합、개배취합화개배역위취합등일계렬가공/“활성”취합기술재합성함당취합물중적응용,병대저일영역소취득적연구진전급현상진행료종술.
The progress of living polymerization techniques has made it possible to design glycopolymers at the molecular level. This paper covers the recent studies on the synthesis of glycopolymers by addressing the mechanisms of cationic polymerization, anionic polymerization, atom transfer radical polymerization (ATRP), reversible addition-fragmentation transfer (RAFT), nitroxide-mediated polymerization (NMP), ring-opening polymerization (ROP) and ring-opening metathesis polymerization (ROMP).